1)diperoxovanadate双过氧钒配合物
1.NMR Studies on Interactions between Diperoxovanadate and 1-Ethyl-1H-Imidazole双过氧钒配合物与N-乙基咪唑相互作用的NMR研究
2.To understand the effects of organic ligands of the diperoxovanadate complexes on the reaction equilibrium,the interactions between a series of diperoxovanadate complexes [OV(O2)2LL']n- [n=1~3;LL'=oxalate,abbr.15mol/L NaCl溶液),应用多核(1H,13C和51V)多维(COSY)NMR以及变温技术等谱学方法研究双过氧钒配合物[OV(O2)2LL']n-[n=1~3,LL'=oxalate(缩写为oxa)、picolinate(缩写为pic)、bipyridine(缩写为bipy)和1,10-phenanthroline(缩写为phen),与它们配位的含钒物种分别缩写为bpV(oxa),bpV(pic),bpV(bipy)和bpV(phen)]与N-甲基咪唑(缩写为N-Me-Im)的相互作用,实验结果表明N-Me-Im与4种双过氧钒配合物的反应活性从强到弱的顺序为:bpV(oxa)>bpV(pic)>bpV(bipy)>bpV(phen)。
3.To understand the substituting effects of organic ligands on the reaction equilibrium, the interac- tions between diperoxovanadate complex [OV(O2)2(D2O)]-/[OV(O2)2(HOD)]- and a series of N-substituted picolinamide ligands in solution were explored using multinuclear (1H, 13C, and 51V) magnetic resonance, COSY, DOSY, and variable temperature NMR in 0.15mol/LNaCl溶液),应用多核(1H,13C和51V)多维(COSY和DOSY)NMR以及变温技术等谱学方法研究双过氧钒配合物[OV(O2)2(D2O)]-/[OV(O2)2(HOD)]-与N-取代皮考啉酰胺的相互作用。
英文短句/例句
1.NMR Studies on Interactions between Diperoxovanadate and 1-Ethyl-1H-Imidazole双过氧钒配合物与N-乙基咪唑相互作用的NMR研究
2.Interactions between Diperoxovanadate and 2-Methyl-imidazole Studied by NMR Spectroscopy双过氧钒配合物与2-甲基咪唑相互作用的NMR研究(英文)
3.Hypoglycemic Effects of Bis (α-furancarboxylato) Oxovanadium (IV) in Alloxan-diabetic Mice and Its Preliminary Mechanisms;新型钒配合物双(α-呋喃甲酸)氧钒的降糖作用及机理分析
4.NMR Studies on Interactions between Diperoxovanadate and Small Organic Molecules;过氧钒配合物与有机小分子相互作用的NMR研究
5.Investigation on the Radical Scavenging Effect of Coordination Complex of Quercetin with Vanadium;槲皮素及其氧钒配合物抗氧化性研究
6.The Study of the Modification of Vanadium-containing Polyoxometalates Using Transition-metal Complexes;含钒多金属氧酸盐的过渡金属配合物修饰化研究
7.Synthesises of Organoperoxovanadium Complexes and Its Catalytic Oxidation of Organic Pollution in Aqueous Solution;过氧钒有机配合物的合成及其对水中有机污染物氧化降解的催化性能研究
8.The Studies on the Biological Activity and Quantization Calculation of the Oxovanadium Complexes;氧钒配合物的生物活性研究及其量化计算
9.Synthesis and Crystal Structure of [VO_2(Sal)(Phen)]·H_2O水杨醛邻菲咯啉氧钒配合物的合成和晶体结构
10.Synthesis,Structure and Quantum Chemistry Calculation of Scorpionate Oxovanadium Complexes with Benzoate蝎型钒氧苯甲酸配合物的合成、结构及量化计算
11.Inhibitory Activities of Some Oxovanadium Complexes with N-Heterocyclic Ligands against PTP1B/ALP含氮杂环氧钒配合物对PTP1B和ALP的抑制活性研究
12.Syntheses and Characterizations of Transition Metal-Aliphitic HydroxylPolycarboxylate Coordination Polymers and Tungsovanadates;过渡金属—脂肪族羟基多羧酸配位聚合物及钨钒金属氧簇的合成与表征
13.Hydrothermal Synthesis of Decavanadium Oxide Complex with 1,10-phenanthroline;以1,10-邻菲罗啉为配体的钒氧酸盐配合物的水热合成
14.Design、Synthesis and Characterization of Oxovanadium Complex Containing Poly (Pyrazolyl) Borate;含有聚吡唑硼酸盐配体的钒氧配合物的设计、合成与表征
15.Synthesis and characterization of ternary oxovanadium(Ⅳ) complexes with polypyridyl and salicylaldehyde alanine Schiff base水杨醛缩丙氨酸Schiff碱氧钒-多吡啶三元混配配合物的合成及表征
16.Studies on Scorpionates Oxovanadium-amino-acid Complex with Potential Biological Activities;具有潜在生物活性的蝎型氧钒氨基酸配合物的研究
17.Synthesis and Characterization of Vanadium Complex with Schiff base 4-Salicylaldehylaminoantipyrine;Schiff碱水杨醛缩4-氨基安替吡啉双核钒(IV)配合物的合成与表征
18.Synthesis, Characterization and Inhibitory Activity in PTP1B of Oxovanadium Compounds with Benzimidazole Ligands苯并咪唑类氧钒配合物的合成、表征及对PTP1B抑制活性研究
相关短句/例句
Diperoxovanadate complex双过氧钒配合物
1.The interaction between diperoxovanadate complex [OV(O2)2(D2O)]-/[OV(O2)2(HOD)]- (abbr.15mol/LNaCl溶液),应用多核(1H和51V)多维(DOSY)NMR以及变温技术等谱学方法研究双过氧钒配合物[OV(O2)(2D2O)]-/[OV(O2)(2HOD)](-简写为bpV)与4,4'-联吡啶(简写为bipy)的相互作用。
3)vanadium(V)-peroxo complexes过氧化钒配合物
1.Singlet oxygen from the photolysis of vanadium(V)-peroxo complexes may be considered as the main contributing reactive oxygen species to the oxidation of thymine base.胸腺嘧啶残基与过氧化钒配合物的光照射反应,由过氧化钒配合物光分解所产生的单线态氧使胸腺嘧啶碱基发生了光氧化反应,可能的反应产物通过核磁共振氢谱进行了测定。
4)peroxovanadate过氧钒配合物
1.NMR Studies on Interactions between Oxalate-oxodiperoxovanadate and Arginine;NMR研究草酸双过氧钒配合物与精氨酸的相互作用
2.It shows that these spectroscopic methods are powerful for analyzing and characterizing the structure and the chemistry of peroxovanadate species in the interaction systems.应用~1H,~(13)C和~(51)V多核NMR技术和电喷雾质谱等谱学手段研究草酸双过氧钒配合物与吡啶、4-甲基咪唑、咪唑等有机配体的相互作用。
5)diperoxovandate双过氧钒化合物
6)organic peroxovanadium complexe过氧钒有机配合物
延伸阅读
钒过氧酸分子式:CAS号:性质:钒酸根离子中的O2-为过氧基团(O22-)取代生成钒的过氧酸。钒原子可以与4、3、2或1个过氧基结合。过氧基数目随溶液的酸碱度不同而异,碱度增加时过氧基数目增加;酸度增加时过氧基数目减少。水溶液中存在钒过氧基的各种平衡反应。在强酸作用下过氧钒酸盐成红色,易分解放出氧。由于反应的灵敏度极高,即使有极少量的钒存在时也容易观察出来。这类反应用于比色法测定钒。