1)pseudorotaxane类轮烷
1.Inthispaper,wereportself-assemblypseudorotaxaneofcucurbit[n]urilwithalkylanediaminesbyusing1HNMRtechniques.以核磁共振谱图分析方法,对以一类新发现的环状化合物—瓜环(cucurbit[n]uril,n=6-8)为主体,链状有机二元胺为客体(轴材)的自组装类轮烷的形成过程及其可能结构进行了初步的研究。
2.In this paper, we report self assembly pseudorotaxane of cucurbit\uril with alkylane diamines by suing 1H NMR spectra (n=5-8).本文以核磁共振谱仪为手段 ,对一类新发现的环状化合物—瓜环 (cucurbit[n]uril,n =5- 8)为主体 ,链状有机胺为轴材的自组装类轮烷的形成过程进行了初步的研究。
3.The structures of self-assembled pseudorotaxane of cucurbit[n]urils(n=6～8) with some alkyldiamines have been investigated by 1H NMR technique and single crystal X-ray diffraction method.1HNMR分析表明瓜环 (Q[6]和Q[7] )与有机二胺 ( 1,7 庚二胺与 1,8 辛二胺 )有较强的相互作用 ,形成自组装类轮烷结构 ;Q[8]与 1,7 庚二胺与 1,8 辛二胺之间相互作用力相对较弱 ;晶体结构测定结果表明 ,六元瓜环与辛二胺自组装形成的类轮烷实体中 ,辛二胺是以直链状穿过六元瓜环的空腔 ,两配位氨基留在瓜环两端口之外 。
英文短句/例句
1.A Study on Pseudorotaxane of Cucurbit[n]uril with Alkylane-diamines;瓜环与有机二元胺形成自组装类轮烷的研究
2.indolylalkylamine alkaloid吲哚基烷基胺类生物碱
3.Preparation and Characterization of Cyclodextrin-based Poly (Pseudo) Rotaxane;环糊精基多聚（准）轮烷的制备及表征
4.Progress of Polyrataxane and Polypseudorotaxane Based on Cyclodextrin基于环糊精的(准)聚轮烷研究进展
5.hydrocarbon gases, usually propane or butane, kept under pressure.烃类气体，通常为储存于高压下的丙烷或丁烷。
6.Antifouling Performance and Adsorption Property of Membrane with Polyrotaxane;含准轮烷滤膜的抗污染及吸附性能研究
7.Synthesis and Characterization of Several Pseudorotaxanes Based on Dibenzo-24-Crown-8-Ether;基于二苯并24-冠-8的几种准轮烷的合成与表征
8.Influence Factors of Self-Assembling Poly(pseudo) rotaxanes with Cyclodextrins环糊精与高分子组装(准)聚轮烷的影响因素
9.Study on the Synthesis of Cyclopropanes and Cyclopropenes;环丙烷和环丙烯类化合物的合成研究
10.Study on Biodegradation of Triphenylmethane Dyes Wastewater;三苯甲烷类染料废水微生物降解研究
11.A Review on Non-methane Hydrocarbons in Air and Seawater大气和海水中非甲烷烃类的研究进展
12.The QSAR study of hallucinogenic phenylalkylamines迷幻性苯烷基胺类化合物的QSAR研究
13.Synthesis of Azetidine Medicinal Intermediates两种氮杂环丁烷类药物中间体的合成
14.Study on the Cycloartane Triterpenes of Actaea asiatiea绿升麻中菠萝蜜烷型三萜类成分研究
15.Synthesis of 1-acetyl-3-alkylazulene derivatives1-乙酰基-3-烷基薁类衍生物的合成
16.Protective effect of thiazolidinediones on the kidney噻唑烷二酮类药物对肾脏的保护作用
17.Whirlpool Qibeng the impeller similar large gas turbines impeller.漩涡气泵的叶轮类似庞大的气轮机的叶轮。
18.Natural gas--Determination of hydrocarbons from butane(C4) to hexadecane(C16)--Gas chromatographic methodGB/T17281-1998天然气中丁烷至十六烷烃类的测定气相色谱法
相关短句/例句
(pseudo)rotaxane/(pseudo)polyrotaxane(类)轮烷/(类)聚轮烷
3)rotaxane轮烷
1.The synthesis of a novel rotaxane containing α-CD(α-cyclodextrin) as the macrocycle,stilbene as the 'string' and the isophthalic acid as stopper via a palladium-catalyzed Suzuki coupling reaction in water at room temperature and supramolecular self-assembly was reported.通过醋酸钯催化的Suzuki偶联反应,在室温下于水溶液中通过超分子自组装制备了以α-CD(α-环糊精)为大环,异酞酸为端塞,二苯乙烯衍生物为链的新型超分子轮烷。
2.Its synthetic strategies, structural characters, properties and applications to the self-assembly of rotaxanes and catenanes are reviewed.详细描述了盒状主体缺π电子联吡啶大环CPQT的结构和性质 ,总结比较了它的各种制备方法 ,并对其与富π电子氢醌醚链衍生物自组装合成索烃、轮烷和准轮烷等方面的应用进行了综述 。
3.This review introduces the synthesis theory, procedure of the rotaxanes and their applications as well.综述了近年来轮烷类化合物的合成原理、合成方法及其应用等方面的研究进展 。
4)pseudopolyrotaxane准聚轮烷
1.Pseudopolyrotaxane Prepared by Supramolecular Self-assembly of Cucurbituril with Polyviologen and Its Properties;葫芦脲与主链聚紫精的超分子自组装制备准聚轮烷及其性质研究
2.Then this copolymer was assembled with α-cyclodextrins in solution formed a novel pseudopolyrotaxane α-CD-PEO-PMPCS.采用原子转移自由基聚合方法(ATRP),以大分子引发剂PEO-Br引发,CuBr/Sparteine体系催化,合成了聚氧化乙烯-聚乙烯基对苯二甲酸二(对甲氧基苯酚)酯(PEO-b-PMPCS)两嵌段聚合物,然后在丙酮和水的混合溶剂中进行嵌段共聚物与α-环糊精的组装,形成了α-CD-PEO-PMPCS的准聚轮烷。
5)monorotaxane单轮烷
1.A novel cucurbit[6]uril monorotaxane bonded silica stationary phase (CB6MRBS) for high performance liquid chromatography has been prepared successfully by combining supramolecular self-assembly technology with the immobilization technique of chromatography stationary phase.将超分子自组装技术与色谱键合硅胶固定相制备技术相结合,采用γ-[(2,3)-环氧丙氧]丙基三甲氧基硅烷(KH-560)为偶联剂,首次将一种葫芦[6]脲单轮烷(CB6MR)键合到硅胶上,制备了一种新型的葫芦[6]脲单轮烷键合固定相(CB6MRBS)。
6)pseudorotaxane准轮烷
1.A Molecular Device Controlled by Acid-Base A New Switch of the Pseudorotaxane Based on Electron Donor Biphenyl Ether Derivatives and Electron Accepter CPQT;可利用酸碱调控的分子器件富电子二苯醚客体和缺电子联吡啶大环组成的准轮烷的“开”与“关”
2.NMR Spectroscopic Studies of a Novel Molecular Pseudorotaxane Controlled by acid-base;可利用酸碱控制的分子器件:准轮烷的“开”与“关”
3.Crystal Structure and DNA Cleavage of [2]Pseudorotaxane Composed of Cucurbit[6]uril;瓜环[2]准轮烷分子晶体结构及切割DNA研究
延伸阅读
十八烷氧基封端二甲基(硅氧烷与聚硅氧烷)CAS：68554-53-0中文名称：十八烷氧基封端二甲基(硅氧烷与聚硅氧烷)英文名称：Siloxanes and Silicones, di-Me, (octadecyloxy)-terminated
