1,6-亚甲基桥[10]轮烯,1,6-methano[10]annulene英语短句,例句大全

1,6-亚甲基桥[10]轮烯,1,6-methano[10]annulene
1)1,6-methano[10]annulene1,6-亚甲基桥[10]轮烯
1.Part one was the syntheses and characterizations of 1,6-methano[10]annulene derivatives.本文第一部分是关于1,6-亚甲基架桥[10]轮烯衍生物的合成及结构表征，首先是以1,6-二甲酰基-1,3,5-环庚三烯为原料，通过10π电子环化反应等反应制备了3-溴代-1,6-亚甲基桥[10]轮烯，通过3-溴代-1,6-亚甲基桥[10]轮烯的碱诱导的偶联反应，简便地合成了3,3'-联-1,6-亚甲基桥[10]轮烯，其次利用和亲二烯化合物的Diels-Alder[4+2]环化反应来进行1,6-亚甲基架桥[10]轮烯与富勒烯的加成反应。
2.Convenient synthesis of 1,6-methano[10]annulene-3,4-dicarboxylic anhydride had been accomplished in 78%yield by the process of saponification and acidification (at r.本论文以1,6-亚甲基桥[10]轮烯-3,4-二甲酸乙酯为原料,经皂化、酸化以78%的产率成功制备了1,6-亚甲基桥[10]轮烯-3,4-二甲酸酐,该酸酐是一种性质很稳定的黄色粉末,可以作为很重要的合成中间体,特别对于开发1,6-亚甲基桥[10]轮烯-3,4-二取代的衍生物有着很重要的意义;为详细研究1,6-亚甲基桥[10]轮烯-3,4-二甲酸酐的性质,以1,6-亚甲基桥[10]轮烯-3,4-二甲酸酐为原料,分别与苯胺、苄胺、苯乙胺、正丁胺在醋酸中回流反应3小时,高产率的制备了N-苯基,N-苄基,N-苯乙基及N-正丁基-1,6-亚甲基桥[10]轮烯-3,4-二甲酰亚胺64a～d,其结构经IR,NMR,Ms及HRMs等谱图进行了确认。
3.A new γ-lactone based on 1,6-methano[10]annulene has been synthesized as follows:The starting material diethyl 1,6-methano[10]annulene-3,4-carboxylate was reduced by LiAlH4 to obtain the corresponding diol,and the diol was subsequently oxidized by BaMnO4 to afford the title γ-lactone in high yield.以1,6-亚甲基桥[10]轮烯-3,4-羧酸二乙酯为原料,经LiAlH4还原得到1,6-亚甲基桥[10]轮烯-3,4-二甲醇,二醇在BaMnO4的氧化下高收率得到一种新型γ-内酯。

英文短句/例句

1.Solvent-free Synthesis of Novel N-amino-substituted 1,6-Methanoannulene-3,4-dicarboximide新型N-氨基取代的1,6-亚甲基桥[10]轮烯-3,4-二甲酰亚胺的无溶剂合成
2.Synthesis of a new γ-lactone based on 1,6-methano[10] annulene一种基于1,6-亚甲基桥[10]轮烯骨架的新型γ-内酯的合成
3.Synthesis and Properties of 1, 6-methano[10]annulene-3, 4-dicarboxylic Anhydride and Its Derivatives1，6-亚甲基桥[10]轮烯-3，4-二甲酸酐及其衍生物的合成与性质的研究
4.Syntheses and Properties of 1, 6-Methano[10]Annulene Derivatives;1，6-亚甲基架桥[10]轮烯衍生物的合成及性质的研究
5.Synergistic scale-inhibition effect of Bis(Hexamethylene Triamine Penta ( Methylene Phosphonic Acid)) and magnetic field on calcium carbonate双1,6-亚己基三胺五亚甲基膦酸与磁场对碳酸钙协同阻垢作用研究
6.The synthesis of dimethyl-hexane-1, 6-dicarbamate (HDU) from 1, 6-Hex anediamine and dimethyl carbonate is a complex reaction system.由1,6-己二胺与碳酸二甲酯制备六亚甲基二氯基甲酸甲酯为一复合反应体系。
7.Studies on Synthesis and Structure of 1 ,6-Di(p-Methoxyphenyl) Dodecamethyl Hexasilane1,6-二(对甲氧苯基)十二甲基六硅烷的合成及结构
8.Polymerization of Methyl Methacrylate by Copper(I) Tert-Butoxide;叔丁醇亚铜催化甲基丙烯酸甲酯聚合
9.Study on Synthesis of 1,7-Bis(3-indolyl)-1,6-heptadiene-3,5-dione1,7-二(3-吲哚基)-1,6-庚二烯-3,5-二酮的合成工艺研究
10.Studies on Ethylene and Methyl Methacrylate Polymerization by Bridged Dinuclear Titanocene;桥联双核钛茂金属催化乙烯及甲基丙烯酸甲酯聚合的研究
11.Reaction of (1,1,2,2 - Tetramethyl Disilanylene) Bis(Tetramethyl - cyclopentadienyl) - Tetracarbonyl Di - Iron with Iodine(1,1,2,2-四甲基二硅桥连)双(四甲基环成二烯基)四羰基二铁与碘的反应
12.and 2-10% acrylic acid, methacrylic acid (III), or itaconic acid, or their mixts.2-10%的丙烯酸、甲基丙烯酸(III)或衣康酸或它们的混合物。
13.Study on Polymerization of Styrene and Methyl Methacrylate by Copper (Ⅰ) Chloride/ethylenediamine/benzyl Chloride;氯化亚铜/乙二胺/苄氯引发苯乙烯和甲基丙烯酸甲酯聚合研究
14.Study on Improving the Thermal Properties of Poly (Methyl Methacrylate) with N-P-tolylmaleimide;N-对甲苯基马来酰亚胺耐热改性聚甲基丙烯酸甲酯的研究
15.S ynthesis of Methylene diacrylamide with Solid acid Catalyst;固体酸催化合成亚甲基双丙烯酰胺的实验研究
16.Synthesis of N,N'-methylenebisacrylamide Using Acidic Ionic Liquid as Catalyst酸性离子液体催化合成N,N’-亚甲基双丙烯酰胺
17.Stability of PVA/DMSO/H_2O in Water Gel聚乙烯醇/二甲基亚砜/水凝胶的稳定性研究
18.Convenient and High Efficient Synthesis of 15β,16β-Methylen-androsta-5-en-3β-ol-17-one简便高效合成15β,16β-亚甲基-雄甾-5-烯-3β-醇-17-酮