1)ferrocenyliminoalcohol二茂铁亚胺醇
2)diferrocenylimine-diols双二茂铁亚胺二醇
1.A novel planar chiral diferrocenylimine-diols 6 was synthesized by the condensation of(R,S_p)-1-(2-diphenyl hydroxyl methyl) ferrocenylethylamine [(R,S_p)-4] with phthaldehyde in anhydrous ethanol,and was crystallographically characterized.通过(R,Sp)-1-(2-二苯基羟甲基)二茂铁乙胺[(R,Sp)-4]和对苯二甲醛在无水乙醇中的缩合反应合成了一种新型平面手性双二茂铁亚胺二醇化合物6,并经X-射线衍射分析它的晶体结构。
3)ferrocenylimine二茂铁亚胺
1.The new type cyclopalladated ferrocenylimines,1 and 2,are synthesized by cyclopalladation of the correspond ferrocenylimines.合成了一种新型二茂铁亚胺环钯化合物1和2,并研究了其催化水相Heck反应,利用紫外光谱、红外光谱、核磁共振以及高效液相色谱等技术手段进行了跟踪测试。
2.In this thesis, a series of novel ferrocenylimines and a cyclometallated ferrocenylimine were synthesized and characterized.本论文主要研究了一系列新型具有刚性结构的二茂铁亚胺及其环金属化合物的合成、表征、电化学性质及在催化Heck反应中的应用。
3.In this thesis, the dioxomolybdenum (Ⅵ) complexes of ferrocenylimine ligands used as novel catalyst for olefin epoxidation were studied in the following four aspects:1.本文对新型二茂铁亚胺钼(Ⅵ)配合物及其用于烯烃环氧化反应催化性能进行了以下四方面的工作:1。
英文短句/例句
1.Synthetic Methods Studies on Ferrocenylketimines and Synthesis of Tertiary Ferrocenylamines;乙酰基二茂铁亚胺合成方法学及苯甲酰二茂铁苄基叔胺的合成
2.Application Studty of Cyclometallated Ferrocenylimines;二茂铁亚胺环金属化合物的应用研究
3.Asymmetric Addition of Organolithium Reagents to Ferrocenylimines有机锂试剂对二茂铁亚胺的不对称加成反应
4.Studies on Cyclopalladated Ferrocenylimines and Au(Ⅰ) Catalyzed Suzuki Cross-coupling Reaction;二茂铁亚胺环钯化合物和Au(Ⅰ)催化的Suzuki偶联反应研究
5.Synthesis and Application of Palladium(Ⅱ), Mercury(Ⅱ) Complexes with Ferrocenylimines and 2-arylnaphthoxazoles;二茂铁亚胺及2-芳基萘骈噁唑钯、汞化合物的合成与应用
6.Synthesis and Application of Heteroannular Cyclopalladated Ferrocenylimines Involving Heterocycle;含杂环二茂铁亚胺异环环钯化合物的合成及应用
7.Studies on the Suzuki Coupling Catalyzed by Phosphine Adducts of Cyclopalladated Ferrocenylimines;环钯化二茂铁亚胺一膦配合物催化的Suzuki反应研究
8.Synthesis of Chiral Cyclopalladated Ferrocenylimines and α-ferrocenyl-α-aminophosphine Oxides and Their Application in Asymmetric Catalysis;手性二茂铁亚胺的环钯化合物和α-胺基膦氧化物的合成及在不对称催化中的应用
9.Cyclopalladated Ferrocenylimines Complexes: Synthesis, Characterization and Application in C-C and C-N Coupling Reactions;二茂铁亚胺环钯化合物的合成、表征及其催化的C-C和C-N偶联反应
10.Synthesis and characterization of two novel ferrocenylimino Schiff-bases containing diphenylphosphinyl groups两种含二苯膦基二茂铁酮亚胺席夫碱的合成与表征
11.Regioselective Cyclopalladation of 1'-benzoyl-1-[(arylimino)phenylmethyl]ferrocene;1’-苯甲酰基-1-[(芳亚胺基)苯甲基]二茂铁区域选择性的环钯化反应
12.Synthesis of Chiral Ferrocenyl Phosphine Ligand and the Application in the Asymmetric Catalysis of Imines;手性二茂铁基膦配体的合成及其在亚胺不对称加成中的应用
13.Synthesis, Characterization and Catalytic Performance of Ferrocenylimine Molybdenum (VI) Complexes for Epoxidation二茂铁基亚胺钼(VI)配合物的合成、表征及催化环氧化性能研究
14.Synthesis and Catalytic Activity of Bis(ferrocenylcarbaldimine) Dioxomolybdenum(VI) Complex双二茂铁基醛亚胺钼(VI)配合物的合成及催化性能
15.Synthesis and Characterization of 1, 1 -Disubstituted Tertiary Ferrocenylamines;1,1 -双取代二茂铁叔胺的合成及表征
16.Synthesis and characterization of diferrocenyl acidamide双二茂铁基酰胺化合物的合成与表征
17.Study on Michael Addition of Amines to Ferrocenyl Chalcones;二茂铁基查耳酮与胺的麦克尔加成反应研究
18.Synthesis and Characterization of Two Series of Aromatic Sec-Amines Bearing Ferrocenyl Group;两类含二茂铁基的芳基仲胺的合成与表征
相关短句/例句
diferrocenylimine-diols双二茂铁亚胺二醇
1.A novel planar chiral diferrocenylimine-diols 6 was synthesized by the condensation of(R,S_p)-1-(2-diphenyl hydroxyl methyl) ferrocenylethylamine [(R,S_p)-4] with phthaldehyde in anhydrous ethanol,and was crystallographically characterized.通过(R,Sp)-1-(2-二苯基羟甲基)二茂铁乙胺[(R,Sp)-4]和对苯二甲醛在无水乙醇中的缩合反应合成了一种新型平面手性双二茂铁亚胺二醇化合物6,并经X-射线衍射分析它的晶体结构。
3)ferrocenylimine二茂铁亚胺
1.The new type cyclopalladated ferrocenylimines,1 and 2,are synthesized by cyclopalladation of the correspond ferrocenylimines.合成了一种新型二茂铁亚胺环钯化合物1和2,并研究了其催化水相Heck反应,利用紫外光谱、红外光谱、核磁共振以及高效液相色谱等技术手段进行了跟踪测试。
2.In this thesis, a series of novel ferrocenylimines and a cyclometallated ferrocenylimine were synthesized and characterized.本论文主要研究了一系列新型具有刚性结构的二茂铁亚胺及其环金属化合物的合成、表征、电化学性质及在催化Heck反应中的应用。
3.In this thesis, the dioxomolybdenum (Ⅵ) complexes of ferrocenylimine ligands used as novel catalyst for olefin epoxidation were studied in the following four aspects:1.本文对新型二茂铁亚胺钼(Ⅵ)配合物及其用于烯烃环氧化反应催化性能进行了以下四方面的工作:1。
4)Ferrocenylimines二茂铁亚胺
1.Chromatographic Features and IR Spectra of Ferrocenylimines and Their Cyclomercurated Derivatives;二茂铁亚胺及其环汞化合物的薄层色谱及紫外-可见、红外光谱特征
2.The article sums up the study and application of cyclopalladated and cyclomercurated ferrocenylimines.综述了二茂铁亚胺环金属化合物二茂铁亚胺环钯、环汞的研究及应用,对二茂铁亚胺环金属化合物的研究进行了总结和展望。
5)ferrocenylaldimine二茂铁醛亚胺
1.The novel chiral cyclopalladated compound 2 was synthesized from the reaction of L-valinol derived ferrocenylaldimine 1 with Li_2PdCl_4/NaOAc followed by treatment with triphenylphosphine.本文中,选用廉价的天然手性缬氨酸为超始原料,将其还原成缬氨醇,与甲酰基二茂铁反应得到手性的二茂铁醛亚胺1,对1的环钯化反应进行了研究,试图利用1中的中心手性诱导出环钯化合物中二茂铁部分的平面手性,分离得到平面手性不同的环钯化非对映异构体(Sp,Sc)-2和(Rp,Sc)-2,遗憾的是,无论是板层析还是重结晶方法均不能将2的一对非对映异构体成功分离。
6)ferrocene imine ester二茂铁亚胺酯
延伸阅读
双嘧哌胺醇分子式:C24H40N8O4分子量:504.62CAS号:58-32-2性质:黄色结晶性粉末。熔点163℃,易溶于氯仿及稀酸,溶于乙醇,微溶于丙酮,几乎不溶于水。无臭,味微苦。制备方法:氨基乳清酸(见02470)经环合、氯化、缩合而得。用途:冠脉扩张剂,用于治疗心绞痛、心肌梗塞等。