1)biphenol双酚配体
1.Single-crystal structure of complex 1 revealedthat the center metal atom is coordinated by six O atoms, four from two biphenol ligands and two from DME mole-cules.研究结果表明,两分子双酚配体中的四个氧原子及一个乙二醇二甲醚(DME)中的两个氧原子与稀土Er进行了配位,而钠离子作为平衡电荷的形式存在。
2)diphenol macrocyclic ligand双酚大环配体
3)Amine bis(phenolate)ligand胺基双酚配体
4)phenolate ligand含酚配体
5)polyaminodiphenol ligands酚胺型配体
6)Diphosphine ligand双膦配体
1.This thesis focused mainly on the designing and synthesis of a series of chiral diphosphine ligands with biphenyl backbone and their application in the asymmetric hydrogenation of acetophenon.本文致力于联苯类手性双膦配体的设计合成,对该类配体三种合成路线进行了考察,通过对文献方法的改进,合成了4个手性双膦配体及11个新的Ru(Ⅱ)-双膦-二胺配合物,并对Ru(Ⅱ)络合物在苯乙酮不对称加氢反应中的催化性能进行了初步考察。
英文短句/例句
1.Synthesis and Applications in Asymmetric Hydrogenation of Chiral Biphenyl Diphosphines and Their Ru(Ⅱ) Complexes;联苯类手性双膦配体及其Ru（Ⅱ）配合物的合成和应用研究
2.Preparation and Application of Para-alkoxy Substituted MeO-BIPHEP-type Diphosphines in Asymmetric Hydrogenation;对烷氧基取代MeO-BIPHEP类手性双膦配体的合成与应用研究
3.Synthesis of Novel Chiral Diphosphine Ligands and Their Application in Asymmetric Catalytic Hydrogenation;新型手性双膦配体的合成及在不对称催化氢化中的应用
4.Design and Synthesis of a Novel Axial Bisphosphine Ligand Induced by Central Chirality, and Their Applications in Catalytic Asymmetric Reaction;中心手性诱导的新型轴手性双膦配体的设计、合成及应用研究
5.Progress of Rhodium/Diphosphine-Catalyzed Homogeneous Hydroformylation of Internal Olefins铑/双膦配体催化均相内烯烃氢甲酰化反应的研究进展
6.Preparation of Novel Tetraphosphonite and P/N Heterobidenate Ligand;新型四膦配体及P、N双齿配体的合成研究
7.The Stereochemistry of Chiral Bisamino Acyl Pentacoordinate Spirophosphoranes手性双氨基酸五配位氢膦烷的立体化学研究
8.Study on Novel Trinuclear PNP Ligand Used in Ethylene Tetramerization新型三核双膦胺（PNP）配体用于乙烯四聚的研究
9.Studies on the Synthesis, Crystal Structure and Characterization of Complexes of Three Types of Disphosphonic Acid;三类双膦酸配体金属配合物的合成、晶体结构及性质研究
10.Synthesis of Chiral Monodentate Phosphorous and Phosphino-Oxazoline Ligands with Spirobiindane Scaffold and Their Applications in Asymmetric Catalytic Reactions;手性螺环单膦和膦—氮配体的合成及应用研究
11.Synthesis and Characterization of Ruthenium and Osmium Complexes Containing Phosphine Ligands;含膦配体钌、锇核配合物的合成与表征
12.Steric and Electronic Effect of Substituents Attached to Nitrogen Atoms of Bis(phosphine)amine Ligand on Catalyst System for Ethylene Tetramerazation双膦胺配体氮原子上取代基的空间和电子效应对于乙烯四聚催化体系的影响
13.Syntheses and Characterizations of Ru-phosphine-diamine Complexes and Applications in Catalytic Hydrogenations of Carbonyl Compounds;钌膦二胺配合物中膦配体的电子效应对羰基催化加氢的影响研究
14.Synthesis and characterization of bis(2-pyridyl)phenylphosphine配体二-(2-吡啶基)苯基膦的合成及表征
15.Preparation and Fluorescence Studies of The Europium and Terbium Complexes with Diphosphonate铕、铽双膦酸酯配合物的合成和荧光性质的研究
16.Synthesis and Characterization of Polydental Pyridylphosphine Ligands and Their Complexes;长链多齿吡啶膦配体及配合物的合成与表征
17.Synthesis and Characterization of Complexes of Multi-phosphines with Transition Metals含多齿膦配体的过渡金属配合物的合成及表征
18.Study on Preparation and Host-guest Chemistry of the Layered Zirconium Diphosphonate;层状双膦酸锆的制备及主—客体化学研究
相关短句/例句
diphenol macrocyclic ligand双酚大环配体
3)Amine bis(phenolate)ligand胺基双酚配体
4)phenolate ligand含酚配体
5)polyaminodiphenol ligands酚胺型配体
6)Diphosphine ligand双膦配体
1.This thesis focused mainly on the designing and synthesis of a series of chiral diphosphine ligands with biphenyl backbone and their application in the asymmetric hydrogenation of acetophenon.本文致力于联苯类手性双膦配体的设计合成,对该类配体三种合成路线进行了考察,通过对文献方法的改进,合成了4个手性双膦配体及11个新的Ru(Ⅱ)-双膦-二胺配合物,并对Ru(Ⅱ)络合物在苯乙酮不对称加氢反应中的催化性能进行了初步考察。
延伸阅读
双酚双酚bisphenolA2，2-双(对羟基苯基)丙烷的简称。
