锌配合物,zinc complex
1)zinc complex锌配合物
1.Four zinc complexes containing ferrocenyl, [Zn(FcCOO)(phen)2]ClO4·FcCOOH (1) (FcCOO=ferrocene-carboxylate, phen=1,10-phenanthroline), [Zn(FcCOO)(phen)2]·ClO4·H2O (2), [Zn(FcCOO)(FcCOGly)(phen)]·C2H5OH (3) (FcCOGly=N-ferrocenylformylglycine), and [Zn(FcCOGly)2(phen)]·CH3OH (4) were synthesized and their crystal structures were determined by X-ray single-crystal diffraction method.合成了4个含二茂铁基的锌配合物[Zn(FcCOO)(phen)2]ClO4·FcCOOH(1)(FcCOO=二茂铁甲酸根,phen=1,10-邻菲咯啉),[Zn(FcCOO)(phen)2]·ClO4·H2O(2),[Zn(FcCOO)(FcCOGly)(phen)]·C2H5OH(3)(FcCOGly=二茂铁甲酰化甘氨酸)和[Zn(FcCOGly)2(phen)]·CH3OH(4)。
2.The study shows that direct electrochemical preparation of zinc complexes such as Zn(acac) 2, Zn(OEt) 2(acac) 2 and Zn(OBu) 2(acac) 2 has high current efficiency and electrolysis yield than that of .采用锌金属为“牺牲”阳极 ,首次在无隔膜电解槽中 ,电化学一步法制备了纳米ZnO前驱体锌配合物Zn(OEt) 2 ,Zn(OBu) 2 ,Zn(acac) 2 ,Zn(OEt) 2 (acac) 2 ,Zn(OBu) 2 (acac) 2 (acac为乙酰丙酮基 ) ,产物通过红外光谱 (FT IR)、拉曼光谱和核磁共振进行表征 。
3.Copper and zinc complexes with macrocyclic Schiff base containing alcohol hydroxyl were synthesized by reaction of 1,3 bis(2 formylphenoxy) 2 propanol with m phenylenediamine by template method.利用模板法合成 1种新的含醇羟基西佛碱型大环冠醚 L (7,11-二氮杂 - 3,15 -二氧杂 - 4 ,5 ;8,10 ;13,14-三苯并环十六 - 6 ,11-二烯 - 1-醇 )的铜、锌配合物
英文短句/例句

1.Synthesis, Structures and Luminescent Properties of Lanthanide and Zinc Complexes;稀土和锌配合物的合成,结构与光谱
2.Synthesis and crystal structure of 3D network Zn(Ⅱ) complex三维网状锌配合物的合成与结构表征
3.Synthesis and Structures of Mannich Ligands and Zinc Complexes;Mannich碱类配体及其锌配合物的合成与结构研究
4.Synthesis and crystal structure of zinc complex with pyrazolyl tridentate ligand含吡唑三齿配体的锌配合物的合成和晶体结构
5.Study and Synthesis of the Complexes of Chitosan and Their Derivatives with Zinc;壳聚糖及其衍生物与锌配合物的合成及研究
6.Complexes of Cd and Zn with 8-Aminoquinoline Ligands: Synthesis, Crystal Structure and Electronic Spectroscopies;8-氨基喹啉镉、锌配合物:合成、结构和光谱性质
7.Synthesis and Spectra Study of Substituted Phthalocyaninatozinc;取代酞菁锌配合物的合成与光谱性质研究
8.Synthesis and Characterization of Zinc Phthalocyanine Complex;酞菁锌配合物的合成及其结构与性质的表征
9.Synthesis and Luminescent Properties of Schiff Bases and Their Zinc Complexes;席夫碱及其锌配合物的合成和发光特性研究
10.Syntheses and Structures of the Nickel (Ⅱ)/Zinc (Ⅱ) Complexes with Schiff Base Ligands Containing N-N Bonds;含N-N键的Schiff碱镍/锌配合物的合成和结构
11.The Synthesis and Characterization of L-alanine Tailed Zinc Porphyrin;新型丙氨酸尾式卟啉锌配合物的合成与表征
12.Study on synthesis and scavenging capacity of free radical of hesperidin-zinc complex橙皮苷锌配合物合成及清除自由基能力的研究
13.Synthesis and Properties of a Novel Porphyrin and Its Zinc Complex新型卟啉及其锌配合物的合成与性质研究
14.Synthesis and Crystal Structure of Zn(Ⅱ) Complex Constructed from 2,3,5,6-Tetramethlytetrephalic Acid四甲基对苯二甲酸锌配合物的合成和晶体结构
15.The Electrochemical Property of L-Alanine Tailed Porphyrin and Its Zinc Complexes;丙氨酸尾式卟啉及其锌配合物的电化学性质
16.SYNTHESIS AND CHARACTERIZATION OF Eu(Ⅲ)-Zn(Ⅱ) BINUCLEAR COMPLEXES铕(Ⅲ)-锌(Ⅱ)双核配合物的合成和表征
17.Synthesis and Characterization of the Complexes of Sodium Ozagrel with Fe(Ⅲ)and Zn(Ⅱ)铁、锌奥扎格雷钠配合物的合成与表征
18.The Study on the Nature of the Coordination Bond in Complexes of Pyridine Zinc;吡啶和取代吡啶锌(Ⅱ)配合物中配键性质的研究
相关短句/例句

zinc complexes锌配合物
1.Theoretical investigation on the photophysical properties of bis(dipyrrinato)zinc complexes;双联吡咯啉类锌配合物的光物理性质的理论研究
2.8-Hydroxyquinoline Derivatives 3 and 4 and their zinc complexes 5 and 6 have been synthesized.设计合成了8-羟基喹啉衍生物3和4以及它们的金属锌配合物5和6,化合物3和4经质谱(MS)、元素分析(EA)、红外光谱(IR)、紫外光谱(UV)、核磁共振氢谱(1HNMR)进行表征,并测定了它们的荧光性质,与2-甲基-8-羟基喹啉(λmax=390nm)比较表明,化合物3和4的荧光红移80~150nm;用X射线单晶衍射仪测定了化合物3的晶体结构,晶体属于三斜晶系,空间群P1,a=0。
3)Zn complex锌配合物
1.A novel Schiff-base ligand and its Zn complex were synthesized and characterized by UV-Vis absorption and photoluminescence spectroscopies.合成了新型席夫碱配体及其锌配合物,并利用核磁共振氢谱、紫外-可见吸收光谱和荧光光谱等方法对配体及其配合物进行了表征。
4)Zn(II) complex锌配合物
1.A trinuclear Zn(II) complex Zn3(L)2(Cl)2(OSO3)2(H2O)2·2H2O (1) (L=N1-(2-aminoethyl)-N1-(2-imidazolethyl)-ethane-1,2-diamine) was synthesized by reaction of ligand L with ZnSO4·7H2O at pH=9 in air.例如人们利用羟乙基二乙烯三胺配体,得到了既有醇羟基又有水分子配位的单核锌配合物,与锌配位的醇羟基的pKa为7。
5)zinic complex锌配合物
6)zinc(Ⅱ)complex锌(Ⅱ)配合物
延伸阅读

外轨配合物和内轨配合物  根据L.C.鲍林的价键理论,具有八面体结构并有4个未成对电子的、顺磁性的[CoF6]3-,或有5个未成对电子的、顺磁性的[Fe(H2O)6]3+,其配位成键杂化轨道为4s4p34d2,所用d 轨道与s和p轨道是属于同一主能级的。这类具有nsnp3nd2形式的配合物(见配位化合物), 因为使用了外层的d轨道,所以叫做外轨配合物。两种配合物的杂化成键轨道分别如图所示。对于具有八面体结构且所有电子都是成对的、抗磁性的[Co(NH3) 6]3+, 或具有1个未成对电子的、 顺磁性的[Fe(CN)6]3-,其成键杂化轨道为3d24s4p3,使用了比s和p轨道低一级主能级层中的d轨道。这类具有(n-1)d2nsnp3型式的配合物,由于使用了内层的d轨道,所以叫做内轨配合物。    在四配位体系中,具有四面体结构且有两个未成对电子的顺磁性的[NiCl4] 2-,其成键杂化轨道为4s4p3,属外轨配合物。而所有电子都成对的、抗磁性的[Ni(CN)4]2-,其成键杂化轨道为3d4s4p2,是平面正方形结构,属内轨配合物。两种配合物的杂化成键轨道如图所示。