1)Fragmentation mechanism裂解机理
1.The mass spectrometric characteristics of phorate and two phosphorothioates are discussed and the chief fragments and fragmentation mechanism are identified with the interpretation of mass spectrum.讨论了甲拌磷及两种硫代磷酸酯的质谱特性 ,并通过质谱解析对主要碎片和裂解机理加以证
2.(1) the respective fragments m/z 176, 191, 192, 193, 161 are formed from molecular ion M~+ on the fragmentation mechanism via various cleavage modes; (2)the base peak at m/z 191 is formed with the loss of a neutral molecule via the ortho effect; (3) the base peak m/z 191 may further be cleaved to form fragments m/z 147, 132, 91; (4) the cleavage of C--N bond in si.本文对2,6—双(二甲胺甲基)—4—乙基酚二盐酸盐这一对称型分子进行了精确质量和亚稳测定,证实了:(1)由分子离子M~+经过多种裂解方式,分别形成相应碎片m/z 176、191、192、193、161的裂解机理;(2)基峰m/z 191是由M~+通过邻位效应失去HN(CH_3)_2中性分子形成的;(3)基峰m/z 191可进一步裂解,通过多种途径形成m/z 147、132、91相应碎片;(4)苯环侧链胺基中C—N键的开裂与非对称型分子相似,而与脂肪胺中C—N键稳定不开裂的过程截然相反。
3.Results show that the atom N is most likely to dissociate in neutral fragment forms of NH2,HCN,HCN2,N3 and N4,while the fragmentation mechanisms are the cleavage of C—N and N—N and the rearrangment.根据质谱图中碎片离子的信息,总结了四氮烯的裂解途径,发现四氮烯裂解时主要有NH2、HCN、HCN2、N3、N4中性碎片的丢失,推测它的裂解机理是C—N、N—N键的断裂反应和分子内重排反应;同时发现四唑环碎片离子m/z68。
英文短句/例句
1.MECHANISM STUDY OF CELLUOSE PYROLYSIS UNDER DIFFERENT TORREFACTION CONDITIONS不同烘焙条件对纤维素热裂解机理的影响研究
2.Study on Degraded Mechanism of High Density Hard to be Degraded Dyeing Waste Water Using Frequency Conversion Ultrasonic Focalize Decomposition Method;高浓度难降解印染废水变频超声聚焦裂解机理的研究
3.Pyrolysis Mechanism of Carbon Matrix Precursor Cyclohexane for the Rapid Densification Process;快速液相沉积致密化工艺碳前驱体环己烷的热裂解机理
4.Coke Deposition in Convection Tubes of Cracking Furnace for Oil Fractions馏份油热裂解炉汽化段结焦机理探讨
5.Control of Products and Mechanism of Degradation during Catalytic Degradation of Polyolefin;聚烯烃催化裂解产物控制与机理研究
6.Experimental Studies on Biomass Pyrolysis Mechanism for Bio-oil and Design of Fluidized-bed Flash Pyrolysis Facility;生物质热裂解制油机理试验研究及流化床闪速热裂解装置设计
7.Analysis on Mechanism of Cleavage Fracture in a Low Alloyed Steel at Different Low Temperature低合金钢在不同低温下解理断裂机理的研究
8.Theoritical Studies on the Pyrolysis Mechanism of Pyridazine哒嗪裂解反应机理的密度泛函理论研究
9.The results provided theoretical basis for down-hole catalytic upgrading of heavy oil.探讨了催化剂对稠油水热裂解反应的催化机理。
10.Mechanism Research of Biomass Pyrolysis on Component Analysis and Kinetic Study;基于组分分析的生物质热裂解动力学机理研究
11.Computational investigation of the enzymatic mechanisms of phosphothreonine lyase苏氨酸磷酸裂解酶催化机理的计算化学研究
12.Overpressure relief mechanisms of cracked gas reservoir in Minfeng area of Dongying Depression东营凹陷民丰地区裂解气藏超压释放机理
13.Research on the Key Technologies of High Consistence and Difficult Decomposition Industrial Wastewater by Ultrasonic Decompose Method;高浓度、难降解有机污水超声聚焦裂解处理关键技术的研究
14.Study on the Mechanism of Thermal Degradation of Diethyl Phthalate by Pyrolysis GC/MS用裂解气相色谱质谱法研究增塑剂DEP热降解机理
15.New Catalysts Studies on the Catalytic Decomposition and Disproportionation Reactions and Mechanism of Organosilicon High-boiling Residue;有机硅高沸物催化裂解制单硅烷新型催化剂研究及机理探讨
16.Theoretical Study of the Olefin Cracking and the Pentene Isomerization over Zeolites;分子筛催化的烯烃裂解及戊烯异构反应机理的理论研究
17.Numerical Simulation of Engine Con-rod Fracture Splitting Process and Analysis on Effect Factors发动机连杆裂解过程数值模拟及裂解参量分析
18.That means PMMA has changed from polar polymer to non-polar polymer.对此现象的解释机理提出了“孔洞”与“极性基团断裂”两种假设。
相关短句/例句
pyrolysis mechanism热裂解机理
1.Based on the thermodynamic data, the pyrolysis mechanism of the carbon matrix toluene used for carbon material was studied by dynamic computation using the UB3LYP/3-21G * method in the Gaussian 98 program package.在热力学研究的基础上 ,用UB3LYP/3 - 2 1G 方法对甲苯热裂解机理进行了动力学研究 。
2.As far as the practical need of Rapid Densification Process of preparing Carbon/Carbon composites was concerned, a theoretical research of the pyrolysis mechanism for three sorts of carbon matrix compounds, including ethylbenzene, p-xylene and cyclohexane, was carried out.以碳/碳(C/C)复合材料快速液相沉积法致密化工艺(RD)的实际需要为出发点,在前期研究的基础上,选择了三种碳源化合物(乙苯、对二甲苯、环已烷)作为研究对象,对其热裂解机理进行了详细的研究,以期了解更多碳源化合物的热裂解机理。
3)mechanism of cleavage fracture解理断裂机理
4)reaction pyrolysis mechanism裂解-反应机理
5)Thermal dewmposition mechanism裂解阻燃机理
6)Ms cleavage mechanism质谱裂解机理
延伸阅读
蒸汽裂解轻芳烃的石脑油与富含1,3-戊二烯蒸汽裂解轻芳烃的石脑油和蒸汽裂解中芳烃的石脑油的聚合物CAS:68527-25-3中文名称:蒸汽裂解轻芳烃的石脑油与富含1,3-戊二烯蒸汽裂解轻芳烃的石脑油和蒸汽裂解中芳烃的石脑油的聚合物英文名称:Naphtha, petroleum, light steam-cracked arom., polymer with light steam-cracked arom. petroleum naphtha piperylene conc. and medium steam-cracked arom. petroleum naphtha naphtha (petroleum), light steam-cracked arom.,polymer with light steam-cracked arom. petroleum naphtha piperyleneconc. and medium steam-cracked arom. petroleum naphtha Naphtha,petroleum,light steam-cracked arom.,polymer with light steam-cracked arom. petroleum naphtha piperylene conc. and medium steam-cracked arom. petroleum naphtha