1)carbomagnesiation碳镁化反应
1.The title compound was synthesized by the carbomagnesiation of phenylmagnesium bromide and 2-phenyl-1-(p-tolylsulfonyl)ethyne.标题化合物可由氰化亚铜催化下的苯基溴化镁与2-苯基-1-对甲苯砜基乙炔的碳镁化反应得到,并用1HNMR,IR和MS对其进行了表征。
2.In the presence of 10%mol of CuCN,carbomagnesiation of 1-pheny-2-(p-tolylsulfonyl)ethyne and p-methylphenylmagnesium bromide gave α-sulfonyl vinyl magnesium reagent,which further reacted with benzaldehyde to obtain the title compound(Z)-1,3-Diphenyl-3-(p-methylphenyl)-2-(p-tolylsulfonyl)-2-propen-1-ol.在10 mol%的CuCN催化下,1-苯基-2-对甲苯砜基乙炔与对甲基苯基溴化镁发生碳镁化反应得到α-砜基烯基格氏试剂,其进一步与苯甲醛反应得到目标产物为α-砜基烯丙醇类化合物(Z)-1,3-二苯基-3-对甲基苯基-2-对甲苯砜基烯丙醇,并将目标产物用1HNMR,13C NMR,IR,Anal。
英文短句/例句
1.Carbomagnesiation of Acetylenic Sulfones and Its Applications in the Synthesis of Polysubstituted Alkenes;炔基砜的碳镁化反应及其在多取代烯烃合成中的应用研究
2.Transition Metal-Catalyzed Carbon-Carbon and Carbon-Nitrogen Cross-Coupling Reactions;过渡金属催化的碳—碳和碳—氮偶联反应
3.Study and Application of Recycled MgO-C and Al_2O_3-MgO-C Bricks再生铝镁碳砖及镁碳砖的研究和应用
4.carbide fuelled breeder碳化物燃料增殖反应堆
5.Experiment and research on magnesium powder passivation by chemical reaction method化学反应法钝化金属镁粒的试验研究
6.EFFECTS OF Mg(CIO_4)_2 ON THE PHOTOOXYDATION OF CHOLESTEROL高氯酸镁对胆甾醇光氧化反应的影响
7.Studies on Preparation of Light Magnesium Carbonate and Magnesia by Stream-recycling Carbonation循环碳化法制备轻质碳酸镁、氧化镁工艺研究
8.Effects of Interfacial Reaction on Tensile Strength of Carbon Fibre Reinforced Magnesium Composites碳纤维增强镁基复合材料的界面反应和拉伸性能研究
9.Precipitation Method Synthesis and Characterization of Basic Magnesium Carbonate and Magnesium Hydroxide沉淀法制备碳酸镁、氢氧化镁的研究
10.The Study on Preparation of the Pure Basic Magnesium Carbonate and Magnesia by Bischofite;水氯镁石制备优质碱式碳酸镁及氧化镁的研究
11.Study on the Preparation of High Pure Magnesium Carbonate and Magnesium Oxide from Byproduct Containing Magnesium Chloride;利用含镁副产品制备高纯碳酸镁及氧化镁研究
12.Surface Coating Technique of Reaction Bonded SiC Mirrors反应烧结碳化硅反射镜表面改性技术
13.Carbonation characteristics of K_2CO_3/Al_2O_3 for CO_2 capture负载型K_2CO_3/Al_2O_3二氧化碳吸收剂的碳酸化反应特性
14.Catalytic Properties of Calcined Mg/Al Layered Double Hydroxides in the Synthesis of Glycol Ethers镁铝复合氧化物在醇醚合成反应中的催化性能
15.co3 graphite reactor二氧化碳冷却石墨慢化反应堆
16.The carbonylation using carbon dioxide as carbon resource;以二氧化碳为C_1资源的羰基化反应
17.Pd/C-catalyzed α-Alkylation of Ketone with Primary Alcohol钯碳催化的酮与伯醇的α-烷基化反应
18.Study on Synthesis of Propylene Carbonate and Dimethyl Carbonate in Supercritical Carbon Dioxide;超临界二氧化碳中碳酸丙烯酯及碳酸二甲酯催化合成反应研究
相关短句/例句
carbonation reaction碳化反应
1.Process analysis and mechanism discussion of carbonation reaction of lithium carbonate;碳酸锂碳化反应过程分析与机理探讨
2.Influence of carbonation reaction to RC structure;碳化反应对钢筋混凝土结构的影响
3.In order to deeply analyze the effect of calcined temperature on the process of nanosized calcium carbonate production,effect of calcination on all kind of technical parameters of slaked reaction and of carbonation reaction was analyzed by testing of limestone calcined at different temperature.为了深入分析石灰石煅烧温度对纳米碳酸钙生产过程的影响,通过对石灰石在不同温度下进行的煅烧试验,分析其对消化反应及碳化反应各项技术指标的影响。
3)carbonization reaction碳化反应
1.Kinetics of carbonization reaction of lithium carbonate;碳酸锂碳化反应动力学研究
4)carbonization[英][,kɑ:b?nai'zei??n][美][,kɑrb?n?'ze??n]碳化反应
5)carbonation reactor碳化反应器
1.New carbonation reactor for the preparation of sphere-like nano-calcium carbonate;生产球形纳米碳酸钙新型碳化反应器开发研究
6)carbonation[kɑ:b?'nei??n]碳酸化反应
1.The carbonation behavior of MgO-CaO powder in CO_2 has been investigated by means of TG-DTG technique.采用TGDTG技术对镁钙砂细粉的碳酸化反应特征进行研究,以阐明镁钙砂碳酸化反应特性。
2.Carbonation reaction mechanism of MgO-CaO powder in CO_2 has been investigated by means of thermogravimetry of single scanning rate of 2 ℃/min for valuable information relevant to the kinetics of surface carbonation of MgO-CaO coarse particles.采用单一扫描速率(2℃/m in)法对镁钙砂细粉的碳酸化反应进行了热分析动力学研究,为镁钙砂颗粒表面碳酸化改性反应动力学研究提供相关信息。
3.Carbonation kinetics of CaO powder in CO_2 has been investigated by means of single scan rate of 2℃/min for information valuable to the kinetics research of surface carbonation of MgO-CaO clinker.采用单一扫描速率法(2℃/min)对氧化钙粉末在CO2气氛中的碳酸化反应进行了热分析动力学研究。
延伸阅读
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