水杨醛亚胺,salicylaldimine
1)salicylaldimine水杨醛亚胺
1.Aqueous polymerizations of ethylene catalyzed by a series of neutral nickel(II) complexes coor- dinated with salicylaldimines have been performed in the presence of surfactants, and the lower branched high molecular weight polyethylene was obtained.在含表面活性剂的水相体系中,用一系列水杨醛亚胺镍配合物催化乙烯聚合,得到了高分子量低支化度聚乙烯。
2.Allyl substituted salicylaldimine and cyclopentenyl substituted salicylaldimine were prepared and reacted with trans [NiCl(Ph)(PPh 3)] to complexes [ O (3 allyl)(5 CH 3)C 6H 2 o C(H)∶N 2,6 C 6H 3( i Pr) 2]Ni (PPh 3)(Ph) and [ O (3 cyclopentenyl)(5 CH 3)C 6H 2 o C(H)∶N 2,6 C 6H 3( i Pr) 2]Ni(PPh 3)(Ph).合成了烯丙基对甲基水杨醛亚胺和环戊烯基对甲基水杨醛亚胺配体 ,并与trans [NiCl(Ph) (PPh3 ) 2 ]反应合成了配合物[O (3 allyl) (5 CH3 )C6H2 o C(H)∶N 2 ,6 C6H3 (i Pr) 2 ]Ni(PPh3 ) (Ph)和 [O (3 cyclopentenyl) (5 CH3 )C6H2 o C(H)∶N 2 ,6 C6H3 (i Pr) 2 ]Ni(PPh3 ) (Ph) ,以MS ,1 HNMR和元素分析对配体及配合物进行了表征 。
3.Allyl salicylaldimine(6) was prepared and reacted with trans-[NiCl(Ph)(PPh 3) 2] to give the salicylaldiminato nickel(Ⅱ) complex(7) ([O-(3-Allyl)C 6H 2[ZJY,0] -ortho-C(H) N-2,6-C 6H 3(i-Pr) 2]Ni(Ph 3-Ni(Ph 3- P)(Ph)).合成了烯丙基水杨醛亚胺配体 (6 ) ,并与trans [NiCl(Ph) (PPh3 ) 2 ]反应合成了配合物 (7)([O (3 Allyl)C6H2 ortho C(H)N 2 ,6 C6H3 (i Pr) 2 ]Ni(Ph3 P) (Ph) ) ,用质谱 ,1HNMR、13 CNMR、IR和元素分析对配体及配合物进行了表征。
英文短句/例句

1.Research Progress in Salicylaldimine Transition Metal Complexes Catalysts for Olefin Polymerization水杨醛亚胺型过渡金属烯烃聚合催化剂研究进展
2.N-(p-dimethylaminophenyl)salicylaldimine as a Highly Selective Receptor for Fluoride AnionN-(对二甲氨基苯基)水杨醛亚胺选择性识别氟离子研究
3.Synthesis, Structure and Reactivity of Organolanthanide Bromide Supported by Salicylaldiminato and 2-(1-(2-ethylamino) Pentyl)-phenol Functionalized-NHC Ligand;水杨醛亚胺(氨基酚)功能化的氮杂环卡宾稀土溴化物的合成,结构及反应性能
4.Synthesis, Characterization of Transition Metal Complexes of Methyl-imino Asymmetric Schiff Bases and Its Catalytic Properties;甲亚胺基水杨醛、吡啶醛类不对称席夫碱配合物的合成、表征及催化性能研究
5.On Highly Selective Salicylating Electrode Based on New Complex of Manganese(Ⅱ)as Neutral Carrier;水杨醛缩丙醇胺Schiff碱锰(Ⅱ)水杨酸根离子选择性电极的研究
6.The Stability Constants of Schiff Base Derived from Salicylalehyde and O,S-Dim ethylphosphoramidothioateand Its Compound of Copper(Ⅱ);水杨醛甲胺磷合铜(Ⅱ)配合物稳定常数测定
7.Study and Application on the Color Reaction of Cobalt(Ⅱ) with Bis(salicyladehyde) ethyenediimine;Co(II)——双水杨醛乙二胺显色反应的研究与应用
8.Synthesis and Crystal Structure of a Cu(Ⅱ) Complex of N-Salicylidene-2-Nitroaniline水杨醛缩邻硝基苯胺合铜的合成与晶体结构
9.The Synthesis of the Metal Complex [Co(Sal_2trien)]Cl二水杨醛三乙基四胺合钴(Ⅲ)金属配合物的合成
10.Synthesis and Antimicrobial Activity of Novel Salicylaldehyde-fluoreyl Amine Schif Base水杨醛-芴胺席夫碱的合成及其抑菌活性
11.Kinetic Study on Electrochemical Oxidation of Alkyl Cobalt Schiff Base Complexes RCo(Salen)双水杨醛缩乙二胺烷基钴(Ⅲ)配合物电化学氧化动力学的研究
12.The Syntheses, Characterization and Property of Schiff Base Metal Complexes Constructed Through Derivatives of Salicylal and 1, 3-Proplenediamine;水杨醛衍生物缩丙二胺Schiff碱金属配合物的合成、表征和性质研究
13.Microwave synthesis in liquid-solid phases for metal complexes of salicylaldehyde with 2-aminoaniline;水杨醛缩邻苯二胺金属配合物的微波液—固相合成
14.Study on the Colour Reaction of Bis (salicylaldehyde) o-phenydnediiminato with Iron (III) and Its Application;双水杨醛邻苯二胺与Fe(III)的显色反应研究及应用
15.Study on the Colour Reaction of Bis(salicylaldehyde) o-phenydnediiminato With Cobalt(Ⅱ) and Its Application;双水杨醛邻苯二胺与Co(Ⅱ)的显色反应研究及应用
16.Synthesis and characterization of a Schiff base from 3-bromo-5-chlorosalicylaldehyde and p-toluidine3-溴-5-氯水杨醛缩对甲基苯胺Schiff碱的合成及晶体结构研究
17.Microwave Assisted Synthesis of 2,2'-[o-phenylenebis(nitrilomethylidyne)] Diphenol and Their Cu(Ⅱ),Ni(Ⅱ) Complexes水杨醛缩邻苯二胺与Cu(Ⅱ)、Ni(Ⅱ)配合物的微波合成
18.Synthesis,crystal structure and biological activity of salicylaldehyde-fluoreylamine Schiff base水杨醛缩2-芴胺席夫碱的合成、晶体结构及生物活性
相关短句/例句

salicylaldiminato水杨醛亚胺
1.A novel post-metallocene metal catalyst of o-benzene salicylaldiminato group ⅣB metal catalyst was synthesized,the complex was supported on SiO2 or MgCl2 and used to prepare catalyst for ethylene polymerization.制备2种新型的过渡金属催化剂——邻苯基水杨醛亚胺钛、锆化合物,研究催化剂在均相条件下和经SiO2、MgCl2负载后的乙烯聚合性能,考察助催化剂与主催化剂摩尔比对乙烯聚合的影响。
2.An o-benzene salicylaldiminato titanium complex was synthesized,and the complex was supported on SiO2 or MgCl2 to prepare catalyst for polyethylene(PE)production.合成了邻苯基水杨醛亚胺钛配合物及其负载SiO2、MgCl2催化剂。
3.We synthesized and characterized neutral lanthanide bromides of L_2SmBr (3-1a), L_2NdBr (3-1b), L_2ErBr (3-1e) and the first cation yttrium bromide [L_2Y]~+Br- (3-2a) supported by salicylaldiminato functionalized N-heterocyclic carbene according to the protonolysis of Ln-N bonds by imidazolium salt B.通过Ln-N键与咪唑盐B的质解反应,成功地合成并表征了中性的水杨醛亚胺功能化的氮杂环卡宾稀土溴化物L_2SmBr (3-1a),L_2NdBr (3-1b),L_2ErBr (3-1e)以及第一个阳离子型金属钇的溴化物[L_2Y]~+Br- (3-2a);通过该配体的锂盐与三氯化钕的复分解反应,同样得到了配合物L_2NdBr (3-1c);利用正丁基锂对亚胺的加成得到的新型三齿氮杂环卡宾配体,合成了相应的金属锂配合物L’2Li2 (3-3a)和阳离子型氮杂环卡宾镱的溴化物[L’_2Yb]~+Br- (3-3b)。
3)salicylaldimine ligand水杨醛亚胺配体
1.Moreover, the effects of Al/Ni ratio, propylene pressure, alkyl aluminum and different substituted groups in salicylaldimine ligand on the reaction were investigated.评价了一系列中性水杨醛亚胺镍 (Ⅱ )膦配合物在烷基铝作用下催化丙烯二聚反应的性能 ,并从铝镍比 ,烷基铝助剂的种类 ,丙烯压力 ,水杨醛亚胺配体上不同取代基等方面进行了考察 。
4)salen双水杨醛亚乙基二亚胺
5)Salicylaldiminato Nickel(II)中性水杨醛亚胺镍
1.Study on the Chain initiation for Olefin Polymerization with Neutral Salicylaldiminato Nickel(II) Catalyst by Density Functional Theory;中性水杨醛亚胺镍催化烯烃聚合反应链引发机理的密度泛函研究
6)salicylaldiminato complex水杨醛亚胺配合物
延伸阅读

一(氧分子)[双(亚水杨醛基)乙二胺基) 吡啶合钴(II)分子式:CAS号:性质:深棕色固体。顺磁性。在-40℃至-l0℃下,用氧气饱和水杨醛钴的吡啶溶液可以制得。用作化学试剂。