插入反应,Insertion reaction
1)Insertion reaction插入反应
1.The insertion reaction mechanism of CCl2 into CH2O has been studied by using the B3LYP/6-311G* and CCSD(T)/6-311G* at single-point.采用密度泛函B3LYP/6-311G*和高级电子相关耦合簇[CCSD(T)/6-311G*]方法计算研究了CCl2与CH2O的插入反应机理,全参数优化了反应势能面各驻点的几何构型,用内禀反应坐标(IRC)和频率分析方法,对过渡态进行了验证。
2.The paper studied catalyzed insertion reaction of α-diazo-β-dicarbonyl compounds into methanol and also investigated influence factors on the reaction, for example structures of diazo and alcohols, catalyst, solvent and reaction temperature.研究了在过渡金属配合物催化下α-重氮-β-二羰基化合物与醇的插入反应,考察了重氮化合物的结构、醇的结构、催化剂的性质、反应溶剂和反应温度对这一反应的影响。
3.The insertion reactions of CX 2 (X=H,F,Cl) with C-H bond in methyl isopropyl ether have been studied at MP2/6 31G(d) level by using ab initio molecular orbital theory.用从头计算方法在MP2 /6 31G(d)水平上研究了CX2 (X =H ,F ,Cl)与甲基异丙基醚的C -H键插入反应
英文短句/例句

1.Insertion Reactions of the Silylenoid H_2C=SiLiBr to RH(R=F,OH,NH_2)类硅烯H_2C=SiLiBr与RH(R=F,OH,NH_2)的插入反应
2.Fully inserted into the reactor, the control rods halt the chain reaction.完全插入反应堆中,控制棒使链式反应暂时停止。
3.Theoretical Investigation on Mechanisms of Rh(Ⅱ)Carbene O-H, S-H Insertion;Rh(Ⅱ)-卡宾O-H,S-H键插入反应机理的理论研究
4.An attendant could cut the rope, dropping the control into the core and preventing a runaway reaction.值班人员可砍断绳索,让控制棒插入反应堆芯从而制止失控反应。
5.Copper(Ⅱ) Trifluoromethanesulfonate Catalyzed Insertion Reaction of Methyl Styryldiazoacetate and Arylamines三氟甲磺酸铜(Ⅱ)催化的苯乙烯基重氮乙酸甲酯和芳胺的插入反应
6.Research in the Synthesis of α-Halo-α, β-Unsaturated Esters and O-H Insertion of α-Diazo Carbonyl Compounds;α-卤代-α,β-不饱和酯的合成与α-重氮羰基化合物O-H插入反应的研究
7.To insert, interpose, or interpolate.插入,使插入,插进
8.The card is unrecognized or not responding. Make sure the card is inserted correctly.无法辨认该卡或该卡没有反应。请确定卡被正确插入。
9.To cause to be inserted by repeated or continuous effort.努力插入经过反复的或不断的努力使被插进去
10.Study of the relationship between the stress response of laryngoscopy tracheal intubation and ABO blood group气管插管应激反应与ABO血型的关系
11.Put the plug in the socket.把插头插入插座里.
12.To plug in(an electrical cord or device) to an outlet.插入插座把(电线或电器)插入插座
13.Influence factors of montmorillonite intercalated quaternary phosphonium salts有机膦/蒙脱土插层反应的影响因素
14.Click here to insert the Vendor Information section.单击此处插入“供应商信息”节。
15.Research and Applictaion of B-spline Curves' Knot Insertion AlgorithmB样条曲线节点插入算法研究及应用
16.The Applications Of Insert Operation In ASPASP中数据库插入操作的几种应用
17.juggling with one's timetable to fit in the extra classes反覆修改自己的时间表以便插入额外课程
18.They have high reflection losses and isolates degree, lower insertion loss.具有高的反射损耗和隔离度,较低的插入损耗。
相关短句/例句

intercalation reaction插入反应
3)insertion reaction of CS_2CS_2插入反应
4)lithium insertion reaction锂插入反应
5)O-H insertion reactionO-H插入反应
1.In addition, the O-H insertion reaction of the α-diazo carbonyl compounds has been exploited.本论文探讨了α-卤代-α,β-不饱和酯的新合成方法以及α-重氮羰基化合物的合成与O-H插入反应
2.Ethyl diazoacetate (EDA) undergoes a facile bis (salicylaldehydato) copper (Ⅱ) carbenoid mediated O-H insertion reaction with ethyl lactate to afford the title compound.重氮乙酸乙酯(EDA)与乳酸乙酯在二水杨醛铜(Ⅱ)催化下进行O-H插入反应合成了α-甲基-缩二乙醇酸二乙酯。
6)N-H insertionN-H插入反应
1.The intermolecular N-H insertion reaction of methyl α-diazo phenylacetate with acetamide has been investigated by catalysis of transition metal complexes and under varying solvent.研究了过渡金属配合物催化剂作用下,不同溶剂中-α重氮苯乙酸甲酯与乙酰胺的分子间N-H插入反应
延伸阅读

插入易位插入易位  指非同源(同形)染色体上的一个断片,易位在另一非同源染色体的中段。此一过程,至少有三处断裂。