Hz, ArCH2) , 4. 00 (d, 1H, 2J =11. 6Hz, PhCH2) , 3. 93 (d, 1H, 2J = 14. 0Hz, ArCH2) , 3. 60 (t, 1H, 3J = 8. 0Hz, CH20), 3. 41 (t, 1H, 3J = 9. 2Hz, CHN), 3. 29 (d, 1H, 2J = 16. 0Hz, NCH2C = N), 2. 83 (d, 1H, 2J = 11. 6Hz,PhCH2), 2. 69(d, 1H, 2J = 16. 0Hz, NCH2C = N), 1. 81 (s, 9H, C(CH3)3), 1. 31 (s, 9H, C(CH3)3), 0. 40 (s, 18H, N (Si (CH3) 3) 2). 13C NMR(C6D6, 100MHz, 298K) :δ 172. 3, 165. 5, 138. 2, 137. 5, 135. 1, 132. 6, 131. 4, 129. 3, 129. 1, 129. Ο, 128. 9, 128. 9, 12 8. 5, 127. 4, 125. 9, 124. 6, 124. Ο, 121. Ο, 112. 6, 76. 6, 65. 6, 63. Ο, 61. 6, 51. 1, 35. 8, 34. 1, 32 .4, 32. 3, 6. 11. Anal. Calcd. For C38H57N302Si2Zn 2: C, 64. 33；H, 8. 10；N, 5. 92. Found:C, 64. 29 ；H, 8. 09；N, 5. 93% .
[0176] 实施例17
[0177] 锌络合物Zn3的合成
[0178]除原料采用Zn[N(SiMe3)2]2(386mg, 1.01mmol)、L3(609mg，l.OOmmol)外，其余操作 步骤同实施例15。得淡黄色固体Zn3 (576mg，69%)。
[0179]
[0180] 4匪R(C6D6, 400MHz，298K) : δ7. 55(d，2H，3J= 7. 6Hz，ArH)，7. 37(d，1H，4J =2. 4Hz, ArH) , 7. 33 - 7. 3 1 (m, 2H, ArH) , 7. 22 - 7. 1 7 (m, 5H, ArH) ,7.13-6. 96 (m, 10H, ArH), 6. 90 - 6. 89 (m, 2H, ArH), 6. 56 (d, 1H, 4J= 2. 4Hz, ArH), 4. 10 (dd, 1H, 3J =7. 2Hz,3J = 10. 0Hz, CH20), 3. 93 (d, 1H, 2J= 14. 0Hz, ArCH2), 3. 81 (d, 1H, 2J= 14. 0Hz, ArCH2), 3. 78 - 3. 72 (m, 2H, 1H of CHO andlH of PhCH2), 3. 53 (dd, 1H, 3J =8.8Hz,3J = 10. 0Hz, CHN), 3. 20 (d, 1H, 2J= 16. 4Hz, CH20), 2. 67 (d, 1H, 2J= 11. 6Hz, PhCH2), 2. 67 (d, 1H, 2J = 16. 4Hz, NCH2C = N), 2. 00 (s, 3H, cumyl-CH3), 2. 00 (s, 3H, c umyl-CH3)，1. 63 (s, 3H, cumyl-CH3)，1. 60 (s, 3H, cumyl-CH3)，0· 30 (s, 18H, N (Si (CH3) 3) 2) · 13C NMR(C6D6, 100MHz, 298K) : δ172. 0, 165. 2, 152. 5, 151. 7, 138. 2, 137. 4, 134. 3, 132. 5, 131. 4, 129. 3, 128. 9, 128. 2, 127. 9, 127. 7, 127. 5, 127. 4, 127. 1, 127. 1, 126. 6, 125. 6, 125. 2, 120. 8 ，76. 9, 65. 1，63. 0, 61. 4, 50. 8, 42. 9, 42. 4, 31. 6, 31. 3, 30. 0, 29. 9, 6. 11. Anal. Calcd. For C4 8H61N302Si2Zn:C, 69. 16；H, 7. 38；N, 5. 04. Found:C, 68. 03；H, 7. 43；N, 4. 82% .
[0181] 实施例18
[0182] 锌络合物Zn4的合成
[0183]除原料采用Zn[N(SiMe3)2]2(600mg，1. 56mmol)、L4(970mg，1. 55mmol)外，其余操作 步骤同实施例15。得无色晶体Zn4(393mg，46%)。
[0184]
[0185] 4匪R(C6D6, 400MHz，298K) : δ 7. 71 (d，6H，3J = 7. 6Hz，ArH), 7. 48(d，1H，4J = 2. 4Hz, ArH), 7. 12 (d, 8H, 3J = 7. 6Hz, ArH), 7. 09 - 7. 00 (m, 5H, ArH), 6. 91(q,5H, 3J = 6. 8Hz, ArH), 6. 80(d, 1H, 3J = 6. 8Hz, ArH), 6. 24 (d, 1H, 4J = 2. 4Hz, ArH), 4. 09 (d, 1H, 2J =14. 0Hz, ArCH2) ,3.99 (d, 1H, 2J = 1 1. 6Hz, PhCH2) , 3. 98 (d, 1H, 2J = 14. OHz, ArCH2) , 3. 71 (dd, 1H, 4J = 4. OHz, 3J = 8.8 Hz, CH20) , 3. 16 (d, 1H, 2J =15. 6Hz, NCH2C = N) , 3. 00 (t, 1H, 3J = 8. 8Hz, CH20) , 2. 90 (d, 2J = 11. 6Hz, PhCH2), 2. 68(d, 1H, 2J = 15. 6Hz, NCH2C = N), 2. 54 (dd, 1H, 4J = 4. OHz, 3J = 8. 8Hz, CHN)，2. 13 (s, 3H, ArCH3)，0· 19 (s, 18H, N (Si (CH3) 3) 2) · 13C匪R (C6D6, 100MHz, 298K) :δ 172. 0, 165. 5, 148. 0, 139. 1, 134. 8, 133. 7, 131. 8, 131. 6, 131. 4, 131. 1, 130. 7, 129. 4, 12 8. 92, 128. 88, 128. 85, 128. 6, 128. 5, 127. 4, 127. 3, 127. 1, 126. 6, 125. 7, 125. 3, 125. 1, 120. 73, 120. 69, 77. 2, 63. 9, 63. 0, 62. 7, 60. 2, 50. 2, 20. 9, 6. 10. Anal. Calcd. For C50H57N302Si2Zn 2 :C, 70. 36；H, 6. 73；N, 4. 92. Found:C, 70. 59；H, 6. 70；N, 4. 67% .
[0186] 实施例19
[0187] 锌络合物Zn5的合成
[0188]除原料采用Zn[N(SiMe3)2]2(391mg，L02mmol)、L5(595mg，LOlmmol)外，其余操作 步骤同实施例15。得白色固体Zn5(213mg，26%)。
[0189]
[0190] 4匪R(C6D6, 400MHz，298K) : δ 7. 70(d，5H，3J = 7. 6Hz，ArH), 7. 52(d，1H，4J =2. 0Hz, ArH), 7. 14 - 7. 10 (m, 14H, ArH), 6. 91 - 6. 88 (m, 5H, ArH), 6. 66 (d, 1H, 4J =2. 0Hz, ArH), 4. 00 (d, 1H, 2J = 11. 2Hz, ArCH2), 3. 67 (dd, 1H, 4J = 4. 0Hz, 3J = 8. 8Hz, CH20), 3. 04 (t, 1H, J = 8. 8Hz, CH20) 2. 69 (d, 1H, 2J = 15. 2Hz, NCH2C = N), 2. 60 (d, 1H, 2J = 11. 2Hz, ArCH2), 2. 58 - 2. 48 (m, 3H, 1H of NCH2C = N, 1H of CHN and 1H of NCH2CH2), 2. 40 (td, 1H, 4J = 4. 4Hz, 3J = 12. 4Hz, NCH2CH2), 2. 30 (s, 3H, ArCH3), 1. 64 - 1. 53 (m, 1H, NCH2CH2), 1. 38 - 1. 27 (m, 1H, NCH2CH2) ,1.13- 1. 01 (m, 2H, CH2CH3) , 0. 88 (t, 3J = 7. 2Hz, CH2CH3). 13C NMR (C6D6, 100MHz, 298K) :δ 171. 7, 165. 3, 148. 0, 139. 2, 134. 8, 133. 7, 131. 6, 131. 1, 129. 3, 128. 9, 128. 6, 127. 4, 127. 2, 125. 2, 120. 9, 120. 6, 77. 4, 63. 9, 63. 0, 61. 2, 59. 7, 51. 2, 26. 9, 21. 1, 20. 9, 14. 1, 6 .01. Anal. Calcd. For C47H59N302Si2Zn:C, 68. 88；H, 7. 26；N, 5. 13. Found:C, 68. 70；H, 7. 30； N, 5. 20% .
[0191] 实施例20
[0192] 锌络合物Zn6的合成
[0193]除原料采用Zn[N(SiMe3)2]2(391mg, L02mmol)、L6(598mg，LOOmmol)外，其余操作 步骤同实施例15。得无色晶体Zn6(481mg，58%)。
[0194]
[0195] 4匪R(C6D6, 400MHz，298K) : δ 7. 70(d，6H，3J = 7. 6Hz，ArH)，7. 52(d，1H，4J =2. 0Hz, ArH) , 7. 1 7 - 7. 0 9 (m, 8H, ArH) , 7. 05 - 7. 0 1 (m, 1H, ArH) ,6.99-6.91(m,5H,ArH),6.68(d, 1H,4J = 2. OHz, ArH) , 4. 1 3 (d, 1H, 2J = 10. 8Hz, ArCH2) , 3. 58 (dd, 1H, 4J = 2. 8Hz, 3J = 8. 4, CH20) , 2. 94 (t, 1H, 3J =8. 4, CH20) , 2. 92 (d, 1H, 2J = 15.2Hz, NCH2C = N) , 2. 76 (d, 1H, 2J = 10. 8Hz, ArCH2), 2. 72 (d, 1H, 2J = 15. 2Hz, NCH2C = N), 2. 56 - 2. 53 (m, 1H, CHN), 2. 30 (s, 3 H, PhCH3)，0· 96 (s, 9H, C (CH3) 3)，0· 13 (s, 18H, N (Si (CH3) 3) 2) · 13C匪R (C6D6, 100MHz, 298K) :δ 173. 0, 165. 4, 148. 0, 139. 9, 134. 5, 133. 6, 131. 9, 131. 6, 128. 8, 128. 6, 127. 50, 127. 46, 125. 2，121. 2，120. 5, 78. 8, 63. 9, 63. 2, 58. 8, 55. 2, 46. 8, 26. 2, 21. 1，6. 44. Anal. Calcd. For C47H59N302Si 2Zn:C，68. 88 ;H，7. 26 ;N，5. 13. Found:C，68. 98 ;H，7. 26 ;N，5. 13% ·
[0196] 实施例21
[0197] 锌络合物Zn7的合成
[0198]除原料采用Zn[N(SiMe3)2]2(390mg，L 02mmol)、L7(600mg，L OOmmol)外，其余操作 步骤同实施例15。得淡黄色固体Zn7 (563mg，68%)。
[0199]
[0200] NMR(C6D6, 400MHz, 298K) : δ 7. 51 (d, 6H/J = 7. 6Hz, ArH), 7. 28 (d, 1Η, 3J =7. 6Hz, ArH), 7. 24 (d, 1H, 4J = 2. 0Hz, ArH), 7. 10 - 7. 02 (m, 3H, ArH), 6. 98 (t, 6H, 3J =7. 6Hz, ArH), 6. 93 - 6. 89 (m, 1H, ArH), 6. 82 - 6. 77 (m, 7H, ArH), 6. 24 (d, 1H, 4J = 2. 0Hz, ArH), 4. 60 (d, 1H, 2J = 12. 0Hz, ArCH2), 4. 27 (d, 1H, 2J = 14. 0Hz, NCH2C = N), 3. 90 (d, 1H, 2J = 14. 0Hz,NCH2C = N), 3. 50 (s, 2H, PhCH2), 3. 19 (d, 1H, 2J = 12. 0Hz ,ArCH2), 1. 99 (s, 3H, ArCH3), 0. 28 (s, 18H, N (Si (CH3) 3) 2). 13C NMR (C6D6, 100MHz, 298K) :δ 168. 0, 151. 2, 147. 9, 136. 8, 136. 0, 133. 7, 131. 90, 131. 87, 131. 7, 131. 54, 131. 47, 129. 0, 127. 06, 127. 03, 126. 4, 125. 7, 125. 2, 120. 91, 120. 85, 120. 3, 110. 8, 64. 1, 61. 2, 60. 1, 45 ? 8, 20. 8, 6. 42. Anal. Calcd. For C48H53N302Si2Zn:C，69. 84 ;H，6. 47 ;N，5. 09. Found:C，69. 75 ; H, 6. 56；N, 5. 00% .
[0201] 实施例22
[0202] 锌络合物Zn8的合成
[0203]除原料采用Zn[N(SiMe3)2]2(390mg，1. 02mmol)、L8(567mg，1. OOmmol)外，其余操作 步骤同实施例15。得无色晶体Zn8(467mg，59%)。
[0204]
[0205] 4匪R(C6D6, 400MHz，298K) : δ 7. 50(d，3H，4J = 1. 2Hz，ArH)，7. 48(d，3H，4J = 1. 2Hz,ArH), 7. 24(d, 1H, 4J = 2. 0Hz, ArH), 7. 20 (d, 1H, 3J = 8. 0Hz, ArH), 6. 99(t,6H, 3J =8. 0Hz, ArH), 6. 91 - 6. 87 (m, 1H, ArH), 6. 83 - 6. 79 (m, 5H, ArH), 6. 52 (d, 1H, 4J = 2. 0Hz, ArH), 4. 45 (d, 1H, 2J = 11. 7Hz, ArCH2), 3. 69 (d, 1H, 2J = 18. 4Hz, NCH2C = N), 3. 23 (d, 1H, 2J = 18. 4Hz,NCH2C = N), 2. 89 (d, 1H, 2J = 11. 7Hz, ArCH2), 2. 10 (s, 3H, ArCH3), 0· 93(s, 9H, NC(CH3)3), 0· 31 (s, 18H, N(Si (CH3)3)2). 13C匪R(C6D6, 100MHz, 298K) :δ 169. 1, 164. 8, 150. 7, 137. 9, 135. 9, 135. 8, 133. 6, 131. 5, 131. 4, 129. 3, 128. 6, 127. 1, 12 6. 1, 125. 7, 125. 5, 125. 1, 121. 3, 121. 3, 120. 7, 110. 5, 64. 1, 59. 6, 55. 7, 44. 9, 21. 4, 20. 9, 6 .60. Anal. Calcd. For C45H55N302Si2Zn [0. 25C7H8] :C, 68. 94；H, 7. 05；N, 5. 16. Found:C, 69. 03 ；H, 6. 95；N, 4. 97% .
[0206] 实施例23
[0207] 锌络合物Zn9的合成
[0208]除原料采用Zn[N(SiMe3)2]2(390mg, 1. 02mmol)、L9(645mg, 1. OOmmol)外，其余操作 步骤同实施例15。得无色晶体Zn9(479mg，55%)。
[0209]
[0210] NMR(C6D6, 400MHz, 298K) : δ 7. 50 - 7. 45 (m, 7H, ArH) , 7. 33 (d, 1H,4J =2. 0Hz, ArH), 6. 99 - 6. 91 (m, 7H, ArH), 6. 85 - 6. 78 (m, 7H, ArH), 6. 63 (d, 1H, 4J =2. 0Hz, ArH), 4. 52 (d, 1H, 2J = 11. 7Hz, ArCH2), 3. 88 (d, 1H, 2J = 18. 7Hz, NCH2C =N), 3. 41 (d, 1H, 2J = 18. 7Hz,NCH2C = N), 3. 04 (d, 1H, 2J = 11. 7Hz, ArCH2), 2. 19 (s, 3H, ArCH3), 1. 83 (br s, 3H, CH (CH2) 3), 1. 69 - 1. 61 (m, 6H, NC (CH2) 3), 1. 42 -1. 39(m, 6H, CHCH2CH), 0. 31 (s, 18H, N(Si (CH3) 3) 2) . 13C NMR (C6D6, 100MHz, 298K) :δ 169. 6, 164. 6, 150. 8, 147. 9, 136. 5, 136. 2, 133. 6, 131. 9, 131.