6, 129. 3, 128. 6, 127. 4, 127. 2, 127. 1, 126. 2, 125. 7, 125. 5, 125. 1, 121. 4, 121. 0, 120. 7, 110. 7, 64. 1, 60. 4, 53. 2, 42. 7, 37. 7, 36. 1, 29. 8, 21. 1, 6. 74. Anal. Calcd. For C51H61N302Si2Zn [0. 2C7Hj：C, 70. 87； H, 7. 11；N, 4. 73. Found:C, 70. 72；H, 7. 25；N, 4. 54% .
[0211] 实施例24
[0212] 锌络合物Znll的合成
[0213]除原料采用Zn[N(SiMe3)2]2(424mg，1.02mmol)、Lll(567mg，l.OOmmol)外，其余操 作步骤同实施例15。得白色固体Znll (319mg，40%)。
[0214]
[0215] NMR(C6D6, 400MHz, 298K) : δ 7. 47(d, 5H, 3J = 7. 6Hz, ArH), 7. 33 (d, 1H, 3J =7. 6Hz, ArH), 7. 31 (d, 1H, 4J = 2. 2Hz, ArH), 6. 94 (t, 7H, 3J = 7. 6Hz, ArH), 6. 86-6. 80 (m, 3H, ArH), 6. 71 (t, 3H, 3J = 7. 2Hz, ArH), 6. 61 (d, 1H, 4J = 2. 0Hz, ArH), 4. 41 (d, 1H, 2J =12. 0Hz, ArCH2) , 3. 75 (d, 1H, 2J = 18. 0Hz, NCH2C = N) , 2. 78 (d, 1H, 2J = 12. 0Hz, ArCH2), 2. 65 (d, 1H, 2J = 18. 0Hz, NCH2C = N), 2. 52 (td, 1H, 4J = 4. 0Hz, 3J = 12. 5, NC H2CH2)，2. 19 (s, 3H, ArCH3)，2. 21 - 2. 10 (m, 1H, NCH2CH2)，1. 82 - 1. 72 (m, 1H, NCH2CH2)，1. 40 - 1. 28 (m, 1H, NCH2CH2), 1. 12 - 1. 03 (m, 1H, CH2CH3), 1. 01 - 0. 93 (m, 1H, CH2CH3), 0. 84 ( t, 3H, 3J = 7. 2Hz,CH2CH3),0. 22(s, 18H, N(Si(CH3)3)2). 13C NMR(C6D6, 100MHz, 298K) :δ 168. 0, 164. 4, 151. 2, 147. 8, 137. 3, 136. 2, 133. 7, 131. 7, 131. 6, 127. 0, 126. 4, 125. 6 ,125. 1, 121. 0, 120. 7, 120. 6, 110. 8, 64. 1, 60. 6, 60. 0, 48. 8, 26. 8, 21. 01, 20. 9, 14. 0, 6. 25. Anal. Calcd. For C45H55N302Si2Zn:C, 68. 29；H, 7. 00；N, 5. 31. Found:C, 67. 72；H, 6. 83； N, 4. 86% .
[0216] 实施例25
[0217] 锌络合物Znl2的合成
[0218]除原料采用Zn[N(SiMe3)2]2(390mg, 1.02mmol)、L12(607mg, l.OOmmol)外，其余操 作步骤同实施例15。得淡紫色固体Znl2 (613mg，74%)。
[0219]
[0220] 4匪R(C6D6, 400MHz，298K) : δ 7. 75(d，6H，3J = 7. 6Hz，ArH), 7. 56(d，1H，4J = 2. 0Hz, ArH), 7. 35 (d, 1H, 3J = 7. 6Hz, ArH), 7. 12 - 7. 07 (m, 8H, ArH), 6. 78 (t, 4H, 3J = 6. 8Hz, ArH), 6. 68 (d, 1H, 4J = 2. 0Hz, ArH), 4. 10 (d, 1H, 3J = 10. 8Hz, CHN), 3. 79 (t, 1H, 3J =7. 2Hz, CHO), 2. 71 (d, 1H, 2J = 15. 6Hz, ArCH2), 2. 70 (d, 1H, 2J = 13. 6Hz, NCH2C = N), 2. 40 (d, J = 15. 6Hz, 1H, ArCH2), 2. 55 - 2. 47 (m, 2H, 1H of NCH2C = N and 1H of CH CH2), 2. 35(s, 3H,ArCH3), 2. 28(d, 3J = 8.0Hz, 1H, CHCH2), 0. 91 (s, 9H, C (CH3) 3), 0. 36 (s, 1 8H, N (Si (CH3) 3) 2) · Anal. Calcd. For C4SH59N302Si2Zn [0· 3C7HS] : C, 70. 03 ;H, 7. 20 ;N, 4. 89. Found:C, 70. 09；H, 7. 26；N, 4. 85% .
[0221] 实施例26
[0222] 锌络合物Zn 13的合成
[0223]除原料采用Zn[N(SiMe3)2]2(390mg, 1.02mmol)、L13(607mg, l.OOmmol)外，其余操 作步骤同实施例15。得无色晶体Znl3(362mg，43%)。
[0224]
[0225] 4匪R(C6D6, 400MHz，298K) : δ 7. 77(d，6H/J = 7. 2Hz，ArH)，7. 57(d，1H，4J = 2. 0Hz, ArH), 7. 31 (d, 1H, 3J = 7. 6Hz, ArH), 7. 10 (t, 6H, 3J = 7. 6Hz, ArH), 6. 97 (d, 2H, 3J = 7. 6Hz, ArH), 6. 79 (d, 3H, 3J = 7. 6Hz, ArH), 6. 75 (d, 1H, 3J = 7. 6Hz, ArH), 6. 67 (d, 1H, 4J = 2. 0Hz, ArH), 4. 02 - 3. 98(m, 2H, CHO and CHN), 2. 65 (d, 1H, 2J = 19. 2Hz, CHCH2), 2. 60-2. 40 (m, 6H, 2H of ArCH2, 2H of NCH2C = N, 1H of CHCH2and 1H of NCH2), 2. 33 (s, 3H ,ArCH3), 2. 31 (td, 1H, 2J = 13. 2Hz, 3J = 4. 4Hz, NCH2), 1. 72 - 1. 61 (m, 1H, CH2), 1. 25 -1. 15 (m, 1H, CH2), 1. 13 - 1. 04 (m, 1H, CH2CH3), 1. 02 - 0. 94 (m, 1H, CH2CH3), 0. 85 (t, 3H, 3J = 7. 2Hz, CH2CH3), 0. 25(s, 18H, N(Si (CH3)3)2). 13C NMR (C6D6, 100MHz, 298K) :δ 171. 0, 165. 2, 147. 9, 139. 5, 138. 7, 134. 8, 133. 7, 132. 0, 131. 6, 131. 0, 129. 1, 127. 6, 1 27. 5, 127. 4, 127. 1, 125. 2, 125. 1, 121. 5, 120. 6, 88. 9, 70. 3, 64. 1, 60. 8, 59. 8, 51. 6, 38. 0, 26. 9, 21. 0, 20. 9, 14. 1, 6. 10. Anal. Calcd. For C48H59N302Si2Zn: C, 69. 33；H, 7. 15；N, 5. 05. Found:C, 69. 24；H, 7. 20；N, 5. 03% .
[0226] 实施例27
[0227] 锌络合物Znl4的合成
[0228]除原料采用Zn[N(SiMe3)2]2(390mg, 1.02mmol)、L14(671mg, l.OOmmol)外，其余操 作步骤同实施例15。得无色晶体Znl4(301mg，34%)。
[0229]
[0230]泊匪R(C6D6, 400MHz，298K) : δ 7. 80(d，5H，3J = 8. 0Hz，ArH), 7. 64(d，1H，4J =2. 0Hz,ArH),7. 19(t, 6H, 3J = 8. 0Hz, ArH), 6. 97 (t, 3H, 3J = 7. 2Hz, ArH), 6. 92-6. 90 (m, 3H, ArH), 6. 85 - 6. 83 (m, 3H, ArH), 6. 72 (d, 1H, 4J = 2. 0Hz, ArH) ,6.64-6. 59 (m, 4H,ArH), 4. 05 - 4. 02 (m, 2H, CHO and CHN), 2. 86 (d, 1H, 2J = 15. 2Hz, ArCH2) , 2. 73 (d, 1H, 2J = 11. 2Hz, NCH2C = N) , 2. 67 (d, 1H, 2J = 15. 2Hz, ArCH2), 2. 62(d, 1H, 2J = 11.2Hz,NCH2C = N), 2. 62 (td, 1H, 2J = 12. 4Hz, 3J =4. 8Hz, NCH2) , 2. 42 (td, 1H, 2J = 12. 4Hz, 3J = 4. 8Hz, NCH2), 2. 18 (s, 3H, Ar CH3), 1. 73 - 1. 62 (m, 1H, CH2), 1. 55 - 1. 44 (m, 1H, CH2), 1. 19 - 1. 10 (m, 2H, CH2CH3), 0. 9 5(t，3H，3J = 7.6Hz，CH2CH3)，0.18(s，18H，N(Si(CH3)3)2).13C匪R(C6D6，100MHz，298K) :δ 174. 0, 165. 8, 148. 3, 134. 7, 134. 5, 133. 2, 133. 1, 131. 4, 130. 8, 128. 5, 128. 4, 127. 7, 12 7. 6, 126. 64, 125. 2, 121. 0, 120. 9, 91. 0, 67. 2, 63. 8, 62. 1, 59. 4, 51. 5, 27. 5, 20. 88, 20. 85, 1 4. 1, 6. 26.
[0231] 实施例28
[0232] 镁络合物Mg4的合成
[0233] 除原料采用1%[1^如]^3)2]2(34611^，1.00臟〇1)、1^(62911^，1.00臟〇1)外，其余操作 步骤同实施例15。得淡黄色固体Mg4(468mg，58% )，两种异构体，比例为3. 3 :1。
[0234]
[0235] NMR(C6D6, 400MHz, 298K) :2isomers(3. 3/l),major: δ 7. 64(d, 6H, 3J = 7. 6Hz, ArH), 7. 42 (s, 1H, ArH), 7. 12 - 6. 86 (m, 19H, ArH), 6. 38 (s, 1H, ArH), 4. 16 (d, 1H, 2J = 12. 0Hz, ArCH2), 4. 00 (d, 1H, 2J = 14. 0Hz, PhCH2), 3. 91 (d, 1H, 2J = 12. 0Hz, ArCH2), 3. 64 - 3. 61 (m, 1H, CH20), 3. 51 (d, 1H, 2J = 14. 0Hz, PhCH2), 3. 39 - 3. 21 (m, 2H, 1H of CH20 and 1H of ArH), 3. 04 - 2. 96 (m, 1H, CHN), 2. 76 (d, 1H, 2J = 16. 8Hz, NCH2C = N), 2. 14 (s, 3H, ArCH3 ),0. 17 (s, 18H, N (Si (CH3) 3) 2) ；minor :5 7.55 (d, 6H, 3J = 7. 6Hz, ArH), 7. 45 (s, 1H, ArH), 7 .35 (s, 1H, ArH), 7. 12 - 6. 86 (m, 17H, ArH), 6. 63 (br s, 2H, ArH), 6. 59 (s, 1H, ArH), 4. 94(t, 1H, 3J = 9. 6Hz, CH20), 3. 96 - 3. 90 (m, 1H, ArCH2), 3. 74 (d, 2H, 2J = 14. 0Hz, ArCH2), 3. 64 - 3. 61 (m, 1H, CH20), 3. 58 (d, 1H, 2J = 8. 8Hz, ArCH2), 3. 39 - 3. 21 (m, 2H, 1H of CHN and 1H of ArCH2), 2. 85 (d, 1H, 2J = 18. 0Hz, ArCH2), 2. 23 (s, 3H, ArCH3) ,0.12 (s, 18H, N (Si (CH3) 3) 2). 1 3C NMR(C6D6, 100MHz, 298K) : δ 173. 1, 164. 5, 148. 0, 139. 3, 135. 2, 133. 6, 131. 8, 131. 8, 131 .7, 131. 1, 129. 3, 129. 2, 128. 99, 128. 96, 128. 6, 128. 6, 127. 3, 126. 9, 125. 2, 121. 0, 120. 4, 77. 3, 64. 3, 64. 0, 61. 1, 60. 4, 48. 2, 21. 0, 6. 34. Anal. Calcd. For C50H57MgN302Si2:C, 73. 91； H, 7. 07；N, 5. 17. Found:C, 73. 55；H, 7. 17；N, 4. 87% .
[0236] 实施例29
[0237] 镁络合物Mg6的合成
[0238] 除原料采用1%[1^如]^3)2]2(34811^，1.00臟〇1)、1^(59611^，1.00臟〇1)外，其余操作 步骤同实施例15。得淡黄色固体Mg6(291mg，37% )，两种异构体，比例为10 :1。
[0239]
[0240] NMR (C6D6, 400MHz) : 2isomers (10/1)，major : δ 7· 69 (d，6 Η，3J= 8. 0Hz, ArH), 7. 52 (s, 1H, ArH), 7. 18 - 6. 88 (m, 14H, ArH), 6. 69 (s, 1H, ArH), 4. 14 (d, 1H, 3J= 10. 8Hz, ArCH2), 3. 52 (d, 1H, 3J= 8. 4Hz, ArCH2), 3. 00(t,1H, 3J= 8. 4Hz, CH20), 2. 90 (d, 1H, 2J =16. 4Hz, ArCH2), 2. 78 - 2. 74 (m, 3H, 1H of CH20, 1H of CHN and 1H of ArCH2), 2. 30 (s, 3 H,ArCH3),0. 91(s, 9H, C(CH3)3),0. 12(s,18H, N(Si (CH3)3)2)；minor: 5 7. 57(s, 1H, ArH), 7. 4 9 (s, 5H, ArH), 7. 44 (s, 1H, ArH), 7. 35-7. 32 (m, 2H, ArH), 7. 18-6. 88 (m, 10H, ArH), 6. 64 (s, 2H ,ArH), 6. 35 (d, 2H, 3J= 7. 2Hz, ArH), 4. 66(t,1H, 3J= 10. 4Hz, CH20), 4. 24 - 4. 22 (m, 1H, ArC H2), 4. 06(t,1H, 3J= 8. 0Hz, CH20), 3. 89(t,1H, 3J= 9. 2Hz, CHN), 3. 67-3. 57 (m, 3H, ArCH2), 2. 67 (s, 3H, ArCH3)，0· 87 (s, 9H, C (CH3) 3)，0· 05 (s, 18H, N (Si (CH3) 3) 2) · 13C NMR (C6D6, 100MHz, 298K) : δ 173. 4, 165. 1, 148. 0, 140. 0, 134. 1, 133. 4, 131. 8, 131. 5, 128. 9, 128. 6, 127. 5, 127 .2, 125. 2, 121. 3, 120. 3, 78. 4, 63. 9, 63. 6, 58. 2, 55. 4, 46. 8, 26. 1, 21. 1, 6. 62. Anal. Calcd. For C47H59MgN302Si2:C，72. 51 ;H，7. 64 ;N，5. 40. Found:C，72. 44 ;H，7. 71 ;N，5. 21% ·
[0241] 实施例30
[0242] 镁络合物Mg8的合成
[0243]除原料采用Mg[N(SiMe3)2]2(350mg，1.01mmol)、L8(567mg，l.OOmmol)外，其余操作 步骤同实施例15。得无色晶体Mg8(377mg，50%)。
[0244]
[0245] NMR(C6D6, 400MHz, 298K) : δ 7. 49 (d, 1H,3J = 8. 0Hz, ArH), 7. 43 (d, 2H, 4J =1. 2Hz, ArH), 7. 41 (d, 2H, 4J = 1. 2Hz, ArH), 7. 34 (d, 1H, 4J = 2. 4Hz, ArH), 6. 95-6. 82 (m, 9H, ArH), 6. 69 - 6. 66 (m, 3H, ArH), 6. 63 (d, 1H, 4J = 2. 4Hz, ArH), 4. 46 (d, 1H, 2J =12. 3Hz, ArCH2) , 3. 89 (d, 1H, 2J = 18. 8Hz, ArCH2) , 3. 02 (d, 1H, 2J = 18. 8Hz, ArCH2) , 3. 00 (d, 1H, 2J = 12. 3Hz, ArCH2) , 2. 21 (s, 3H, ArCH3) ,0.83 (s, 9H, NC (CH3) 3) , 0. 34